{"title":"用于不对称电容器应用的 MnMoO4 装饰 MWCNT 纳米复合板的电化学性能","authors":"N. Jafarulla , Shanmugaiah Mathan Kumar","doi":"10.1016/j.diamond.2024.111743","DOIUrl":null,"url":null,"abstract":"<div><div>To improve advanced energy storage systems, innovative and versatile electrode materials with exceptional electrochemical characteristics must be developed. In this study, we present a new and distinctive design for an electrode made of MWCNT nanowires decorated on plates like MnMoO<sub>4</sub>. The nanocomposite was fabricated using a hydrothermal method and developed for use in an asymmetric supercapacitor. Initially, the samples underwent thorough examination using spectroscopic techniques such as XRD and XPS, as well as microscopic investigation using FE-SEM. The sample provides an effective mesoporous structure, facilitates the flow of ions, enables fast electron transfer, and permits a higher concentration of MnMoO<sub>4</sub> and MWCNT active sites. The MnMoO<sub>4</sub>/MWCNT composite has a specific capacitance (C<sub>s</sub>) of 1800 F/g at 1 A g<sup>−1</sup>, demonstrating excellent durability in a three-electrode cell. The built asymmetric supercapacitors demonstrate a power density of 1062 W kg<sup>−1</sup> and an energy density of 42.48 Wh kg<sup>−1</sup>. Furthermore, the ASCs exhibit remarkable cycling stability, with about 93% capacity retention after undergoing 10,000 cycles. Therefore, the current work clearly shows its effective due to its excellent electrochemical properties, this material shows great potential to be used in storage systems for energy.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"151 ","pages":"Article 111743"},"PeriodicalIF":4.3000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical performance of MnMoO4-decorated MWCNT nanocomposite plates for asymmetric capacitor applications\",\"authors\":\"N. Jafarulla , Shanmugaiah Mathan Kumar\",\"doi\":\"10.1016/j.diamond.2024.111743\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>To improve advanced energy storage systems, innovative and versatile electrode materials with exceptional electrochemical characteristics must be developed. In this study, we present a new and distinctive design for an electrode made of MWCNT nanowires decorated on plates like MnMoO<sub>4</sub>. The nanocomposite was fabricated using a hydrothermal method and developed for use in an asymmetric supercapacitor. Initially, the samples underwent thorough examination using spectroscopic techniques such as XRD and XPS, as well as microscopic investigation using FE-SEM. The sample provides an effective mesoporous structure, facilitates the flow of ions, enables fast electron transfer, and permits a higher concentration of MnMoO<sub>4</sub> and MWCNT active sites. The MnMoO<sub>4</sub>/MWCNT composite has a specific capacitance (C<sub>s</sub>) of 1800 F/g at 1 A g<sup>−1</sup>, demonstrating excellent durability in a three-electrode cell. The built asymmetric supercapacitors demonstrate a power density of 1062 W kg<sup>−1</sup> and an energy density of 42.48 Wh kg<sup>−1</sup>. Furthermore, the ASCs exhibit remarkable cycling stability, with about 93% capacity retention after undergoing 10,000 cycles. Therefore, the current work clearly shows its effective due to its excellent electrochemical properties, this material shows great potential to be used in storage systems for energy.</div></div>\",\"PeriodicalId\":11266,\"journal\":{\"name\":\"Diamond and Related Materials\",\"volume\":\"151 \",\"pages\":\"Article 111743\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Diamond and Related Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925963524009567\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Diamond and Related Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925963524009567","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
Electrochemical performance of MnMoO4-decorated MWCNT nanocomposite plates for asymmetric capacitor applications
To improve advanced energy storage systems, innovative and versatile electrode materials with exceptional electrochemical characteristics must be developed. In this study, we present a new and distinctive design for an electrode made of MWCNT nanowires decorated on plates like MnMoO4. The nanocomposite was fabricated using a hydrothermal method and developed for use in an asymmetric supercapacitor. Initially, the samples underwent thorough examination using spectroscopic techniques such as XRD and XPS, as well as microscopic investigation using FE-SEM. The sample provides an effective mesoporous structure, facilitates the flow of ions, enables fast electron transfer, and permits a higher concentration of MnMoO4 and MWCNT active sites. The MnMoO4/MWCNT composite has a specific capacitance (Cs) of 1800 F/g at 1 A g−1, demonstrating excellent durability in a three-electrode cell. The built asymmetric supercapacitors demonstrate a power density of 1062 W kg−1 and an energy density of 42.48 Wh kg−1. Furthermore, the ASCs exhibit remarkable cycling stability, with about 93% capacity retention after undergoing 10,000 cycles. Therefore, the current work clearly shows its effective due to its excellent electrochemical properties, this material shows great potential to be used in storage systems for energy.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.