Shigao Chen , Xuemei Yao , Yue Yang , Ya Yang , Yufeng Du , Yun Cheng , Mohan Yu , Xianchao Du , Huajuan Deng , Ruijin Yu
{"title":"一种新型远红外荧光粉 Ca2InTaO6:Mn4+ 对植物生长所需的植物色素 PFR 具有极佳的响应性","authors":"Shigao Chen , Xuemei Yao , Yue Yang , Ya Yang , Yufeng Du , Yun Cheng , Mohan Yu , Xianchao Du , Huajuan Deng , Ruijin Yu","doi":"10.1016/j.ceramint.2024.09.429","DOIUrl":null,"url":null,"abstract":"<div><div>A series of novel Ca<sub>2</sub>InTaO<sub>6</sub> perovskite compounds doped with Mn<sup>4+</sup> ions were successfully synthesized via the conventional solid-state method at elevated temperatures. The X-ray powder diffraction (XRD) technique was utilized to capture the phase structure. Based on the analysis of diffuse reflection (DR) spectra and density functional theory (DFT) calculations, it can be concluded that Ca<sub>2</sub>InTaO<sub>6</sub> exhibits characteristics of an indirect semiconductor with a band gap <em>E</em><sub>g</sub> = 3.526 eV. With a 367 nm excitation, the Mn<sup>4+</sup>-doped Ca<sub>2</sub>InTaO<sub>6</sub> exhibits a far-red emission at 689 nm, corresponding to the <sup>2</sup>E<sub>1g</sub> to <sup>4</sup>A<sub>2g</sub> transition. The photoluminescence (PL) characteristics of the sample align well with the absorption properties of phytochrome far-red light (P<sub>FR</sub>). Based on analysis using the Tanabe-Sugano diagram, it can be inferred that Mn<sup>4+</sup> is situated in a highly intense crystalline field for the <sup>2</sup>E<sub>1g</sub> state. At concentration <em>x</em> = 0.006, the most optimal Mn<sup>4+</sup> doping was achieved, ascribing to the nearest neighbour ion interaction. The internal quantum efficiency (IQE) is 35.48 %. The Commission International del'Eclairage (CIE) coordinates of a red LED fabricated with Ca<sub>2</sub>InTaO<sub>6</sub>:0.006Mn<sup>4+</sup> phosphor is located in the red region. Moreover, the electroluminescent spectrum (EL) exhibited by the enclosed lamp has a larger overlapping with the chlorophyll P<sub>FR</sub> (85.68 %) than P<sub>R</sub> (22.27 %) absorption spectra for promoting plant growth. This study not only provides detailed guidelines for evaluating the practical usability enhancing the P<sub>R</sub> to P<sub>FR</sub> conversion of Ca<sub>2</sub>InTaO<sub>6</sub>:0.006Mn<sup>4+</sup>, but also presents a thorough examination of the luminescent characteristics demonstrated by the Mn<sup>4+</sup> activators.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 50821-50833"},"PeriodicalIF":5.1000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A novel far-red-emitting phosphor Ca2InTaO6:Mn4+ with excellent responsiveness to phytochrome PFR for plant growth\",\"authors\":\"Shigao Chen , Xuemei Yao , Yue Yang , Ya Yang , Yufeng Du , Yun Cheng , Mohan Yu , Xianchao Du , Huajuan Deng , Ruijin Yu\",\"doi\":\"10.1016/j.ceramint.2024.09.429\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of novel Ca<sub>2</sub>InTaO<sub>6</sub> perovskite compounds doped with Mn<sup>4+</sup> ions were successfully synthesized via the conventional solid-state method at elevated temperatures. The X-ray powder diffraction (XRD) technique was utilized to capture the phase structure. Based on the analysis of diffuse reflection (DR) spectra and density functional theory (DFT) calculations, it can be concluded that Ca<sub>2</sub>InTaO<sub>6</sub> exhibits characteristics of an indirect semiconductor with a band gap <em>E</em><sub>g</sub> = 3.526 eV. With a 367 nm excitation, the Mn<sup>4+</sup>-doped Ca<sub>2</sub>InTaO<sub>6</sub> exhibits a far-red emission at 689 nm, corresponding to the <sup>2</sup>E<sub>1g</sub> to <sup>4</sup>A<sub>2g</sub> transition. The photoluminescence (PL) characteristics of the sample align well with the absorption properties of phytochrome far-red light (P<sub>FR</sub>). Based on analysis using the Tanabe-Sugano diagram, it can be inferred that Mn<sup>4+</sup> is situated in a highly intense crystalline field for the <sup>2</sup>E<sub>1g</sub> state. At concentration <em>x</em> = 0.006, the most optimal Mn<sup>4+</sup> doping was achieved, ascribing to the nearest neighbour ion interaction. The internal quantum efficiency (IQE) is 35.48 %. The Commission International del'Eclairage (CIE) coordinates of a red LED fabricated with Ca<sub>2</sub>InTaO<sub>6</sub>:0.006Mn<sup>4+</sup> phosphor is located in the red region. Moreover, the electroluminescent spectrum (EL) exhibited by the enclosed lamp has a larger overlapping with the chlorophyll P<sub>FR</sub> (85.68 %) than P<sub>R</sub> (22.27 %) absorption spectra for promoting plant growth. This study not only provides detailed guidelines for evaluating the practical usability enhancing the P<sub>R</sub> to P<sub>FR</sub> conversion of Ca<sub>2</sub>InTaO<sub>6</sub>:0.006Mn<sup>4+</sup>, but also presents a thorough examination of the luminescent characteristics demonstrated by the Mn<sup>4+</sup> activators.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 50821-50833\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S027288422404464X\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S027288422404464X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
A novel far-red-emitting phosphor Ca2InTaO6:Mn4+ with excellent responsiveness to phytochrome PFR for plant growth
A series of novel Ca2InTaO6 perovskite compounds doped with Mn4+ ions were successfully synthesized via the conventional solid-state method at elevated temperatures. The X-ray powder diffraction (XRD) technique was utilized to capture the phase structure. Based on the analysis of diffuse reflection (DR) spectra and density functional theory (DFT) calculations, it can be concluded that Ca2InTaO6 exhibits characteristics of an indirect semiconductor with a band gap Eg = 3.526 eV. With a 367 nm excitation, the Mn4+-doped Ca2InTaO6 exhibits a far-red emission at 689 nm, corresponding to the 2E1g to 4A2g transition. The photoluminescence (PL) characteristics of the sample align well with the absorption properties of phytochrome far-red light (PFR). Based on analysis using the Tanabe-Sugano diagram, it can be inferred that Mn4+ is situated in a highly intense crystalline field for the 2E1g state. At concentration x = 0.006, the most optimal Mn4+ doping was achieved, ascribing to the nearest neighbour ion interaction. The internal quantum efficiency (IQE) is 35.48 %. The Commission International del'Eclairage (CIE) coordinates of a red LED fabricated with Ca2InTaO6:0.006Mn4+ phosphor is located in the red region. Moreover, the electroluminescent spectrum (EL) exhibited by the enclosed lamp has a larger overlapping with the chlorophyll PFR (85.68 %) than PR (22.27 %) absorption spectra for promoting plant growth. This study not only provides detailed guidelines for evaluating the practical usability enhancing the PR to PFR conversion of Ca2InTaO6:0.006Mn4+, but also presents a thorough examination of the luminescent characteristics demonstrated by the Mn4+ activators.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.