{"title":"在液体中通过飞秒激光烧蚀制造碳化硅彩色中心纳米粒子","authors":"Jianshi Wang, Bing Dong, Ying Song, Mengzhi Yan, Qingqing Sun, Zongwei Xu","doi":"10.1016/j.ceramint.2024.10.021","DOIUrl":null,"url":null,"abstract":"<div><div>Combined with the fabrication of low-dimensional materials, certain silicon carbide color centers can become excellent platforms for nano-optics, and be applied to quantum and biomedical fields. In this work, color center nanoparticles were prepared based on high purity semi-insulating silicon carbide substrate using liquid-assisted femtosecond laser machining. Effects of multi-pulse array ablation and line scanning fabrication were investigated, and parameters such as repetition frequency and pulse number were also optimized. We employed photoluminescence spectroscopy, field emission scanning electron microscopy and transient fluorescence spectroscopy to characterize optical properties and micromorphology of nanoparticles. The broadband photoluminescence within the range of 850–950 nm should be attributed to silicon vacancy color centers, and V1/V1’ zero-phonon lines were confirmed at low temperature. It is noted that the femtosecond laser annealing is critical for the luminescence enhancement of color center nanoparticles. The evolution of particles and cavitation bubbles during processing was elucidated. After optimization, silicon vacancy color center nanoparticles were prepared by multi-pulse (10<sup>7</sup>) array ablation and 200 kHz pulse repetition frequency, with an average diameter of approximately 15 nm and an average density reaching 273.94 counts/μm<sup>2</sup>. The sample can be preserved stably in the form of nanoparticle solutions. Processing methods and corresponding conclusions of this study would be applicable to the femtosecond laser fabrication and micromorphology control of color center nanoparticles of various hard-brittle semiconductors.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 51098-51110"},"PeriodicalIF":5.1000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of silicon carbide color center nanoparticles by femtosecond laser ablation in liquid\",\"authors\":\"Jianshi Wang, Bing Dong, Ying Song, Mengzhi Yan, Qingqing Sun, Zongwei Xu\",\"doi\":\"10.1016/j.ceramint.2024.10.021\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Combined with the fabrication of low-dimensional materials, certain silicon carbide color centers can become excellent platforms for nano-optics, and be applied to quantum and biomedical fields. In this work, color center nanoparticles were prepared based on high purity semi-insulating silicon carbide substrate using liquid-assisted femtosecond laser machining. Effects of multi-pulse array ablation and line scanning fabrication were investigated, and parameters such as repetition frequency and pulse number were also optimized. We employed photoluminescence spectroscopy, field emission scanning electron microscopy and transient fluorescence spectroscopy to characterize optical properties and micromorphology of nanoparticles. The broadband photoluminescence within the range of 850–950 nm should be attributed to silicon vacancy color centers, and V1/V1’ zero-phonon lines were confirmed at low temperature. It is noted that the femtosecond laser annealing is critical for the luminescence enhancement of color center nanoparticles. The evolution of particles and cavitation bubbles during processing was elucidated. After optimization, silicon vacancy color center nanoparticles were prepared by multi-pulse (10<sup>7</sup>) array ablation and 200 kHz pulse repetition frequency, with an average diameter of approximately 15 nm and an average density reaching 273.94 counts/μm<sup>2</sup>. The sample can be preserved stably in the form of nanoparticle solutions. Processing methods and corresponding conclusions of this study would be applicable to the femtosecond laser fabrication and micromorphology control of color center nanoparticles of various hard-brittle semiconductors.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 51098-51110\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224045334\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224045334","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Fabrication of silicon carbide color center nanoparticles by femtosecond laser ablation in liquid
Combined with the fabrication of low-dimensional materials, certain silicon carbide color centers can become excellent platforms for nano-optics, and be applied to quantum and biomedical fields. In this work, color center nanoparticles were prepared based on high purity semi-insulating silicon carbide substrate using liquid-assisted femtosecond laser machining. Effects of multi-pulse array ablation and line scanning fabrication were investigated, and parameters such as repetition frequency and pulse number were also optimized. We employed photoluminescence spectroscopy, field emission scanning electron microscopy and transient fluorescence spectroscopy to characterize optical properties and micromorphology of nanoparticles. The broadband photoluminescence within the range of 850–950 nm should be attributed to silicon vacancy color centers, and V1/V1’ zero-phonon lines were confirmed at low temperature. It is noted that the femtosecond laser annealing is critical for the luminescence enhancement of color center nanoparticles. The evolution of particles and cavitation bubbles during processing was elucidated. After optimization, silicon vacancy color center nanoparticles were prepared by multi-pulse (107) array ablation and 200 kHz pulse repetition frequency, with an average diameter of approximately 15 nm and an average density reaching 273.94 counts/μm2. The sample can be preserved stably in the form of nanoparticle solutions. Processing methods and corresponding conclusions of this study would be applicable to the femtosecond laser fabrication and micromorphology control of color center nanoparticles of various hard-brittle semiconductors.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.