Bingsen Wang , Junjun Wang , Yuxiao Du , Jian Dai , Zhenhao Fan , Wenfeng Yue , Fu Huang , Atilla Evcin , Yasemin Tabak , Limei Zheng , Dawei Wang
{"title":"掺杂 BiFeO3 的 NaNbO3 反铁电陶瓷的卓越储能特性","authors":"Bingsen Wang , Junjun Wang , Yuxiao Du , Jian Dai , Zhenhao Fan , Wenfeng Yue , Fu Huang , Atilla Evcin , Yasemin Tabak , Limei Zheng , Dawei Wang","doi":"10.1016/j.ceramint.2024.09.403","DOIUrl":null,"url":null,"abstract":"<div><div>NaNbO<sub>3</sub> (NN)-based dielectric ceramics for energy storage have garnered significant interest due to their high saturation polarization, low residual polarization, and superior breakdown strength (<em>E</em><sub>b</sub>). However, the low recoverable energy storage density (<em>W</em><sub>rec</sub>) and efficiency (<em>η</em>) significantly limited their practical application. Herein, BiFeO<sub>3</sub> (BF) was incorporated into NN to optimize the energy storage performance. The NN-BF ceramics exhibited pronounced antiferroelectric (AFE) relaxor phase, alongside grain size reduction and <em>E</em><sub>b</sub> enhancement, which contributed to a significant increase of <em>W</em><sub>rec</sub> and <em>η</em>. Specially, the optimum <em>W</em><sub>rec</sub> of 4.43 J/cm³ and <em>η</em> of 71.51 % were achieved at the composition of 0.9NN-0.1BF. Besides, stable energy storage performance was maintained over a wide temperature range (20–120 °C). These results highlight the potential of NN-BF relaxor AFE ceramics as promising candidates for high-performance energy storage applications.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"50 23","pages":"Pages 50587-50594"},"PeriodicalIF":5.1000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Superior energy storage properties of BiFeO3 doped NaNbO3 antiferroelectric ceramics\",\"authors\":\"Bingsen Wang , Junjun Wang , Yuxiao Du , Jian Dai , Zhenhao Fan , Wenfeng Yue , Fu Huang , Atilla Evcin , Yasemin Tabak , Limei Zheng , Dawei Wang\",\"doi\":\"10.1016/j.ceramint.2024.09.403\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>NaNbO<sub>3</sub> (NN)-based dielectric ceramics for energy storage have garnered significant interest due to their high saturation polarization, low residual polarization, and superior breakdown strength (<em>E</em><sub>b</sub>). However, the low recoverable energy storage density (<em>W</em><sub>rec</sub>) and efficiency (<em>η</em>) significantly limited their practical application. Herein, BiFeO<sub>3</sub> (BF) was incorporated into NN to optimize the energy storage performance. The NN-BF ceramics exhibited pronounced antiferroelectric (AFE) relaxor phase, alongside grain size reduction and <em>E</em><sub>b</sub> enhancement, which contributed to a significant increase of <em>W</em><sub>rec</sub> and <em>η</em>. Specially, the optimum <em>W</em><sub>rec</sub> of 4.43 J/cm³ and <em>η</em> of 71.51 % were achieved at the composition of 0.9NN-0.1BF. Besides, stable energy storage performance was maintained over a wide temperature range (20–120 °C). These results highlight the potential of NN-BF relaxor AFE ceramics as promising candidates for high-performance energy storage applications.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"50 23\",\"pages\":\"Pages 50587-50594\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2024-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884224044389\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884224044389","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Superior energy storage properties of BiFeO3 doped NaNbO3 antiferroelectric ceramics
NaNbO3 (NN)-based dielectric ceramics for energy storage have garnered significant interest due to their high saturation polarization, low residual polarization, and superior breakdown strength (Eb). However, the low recoverable energy storage density (Wrec) and efficiency (η) significantly limited their practical application. Herein, BiFeO3 (BF) was incorporated into NN to optimize the energy storage performance. The NN-BF ceramics exhibited pronounced antiferroelectric (AFE) relaxor phase, alongside grain size reduction and Eb enhancement, which contributed to a significant increase of Wrec and η. Specially, the optimum Wrec of 4.43 J/cm³ and η of 71.51 % were achieved at the composition of 0.9NN-0.1BF. Besides, stable energy storage performance was maintained over a wide temperature range (20–120 °C). These results highlight the potential of NN-BF relaxor AFE ceramics as promising candidates for high-performance energy storage applications.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.