使用新型双功能异构催化剂将非食用油一锅转化为可持续生物柴油

IF 9 1区 工程技术 Q1 ENERGY & FUELS
Rida Ihsan, Abdul Naeem, Muhammad Farooq, Tooba Saeed, Muhammad Noman, Ghazala Abid, Tabassum Malik
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引用次数: 0

摘要

本研究旨在使用新型双功能 xK2O/ZrO2-Bi2O3 催化剂从本地非食用原料野生橄榄籽油中生产生物柴油。所设计的催化剂采用溶胶凝胶浸渍法制备。利用各种分析技术,包括 EDX、FTIR、XRD、SEM、BET 和 XPS,阐明了合成催化剂的质地和表面特性。在优化的反应条件下,催化剂的生物柴油产率最高,达到 95.2%。生物柴油的成功合成得到了气相色谱、核磁共振和傅立叶变换红外分析的证实,而各种理化性质则根据 ASTM 和 EN 标准进行了研究。所设计的催化剂具有很高的可重复性和可回收性,最多可回收四次。此外,还提出了 xK2O/ZrO2-Bi2O3 催化 WOSO 酯交换反应的机理。动力学研究表明,该反应遵循假一阶,计算得出的 Ea 为 32.58 kJ mol-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

One-pot conversion of non-edible oil into sustainable biodiesel using novel bifunctional heterogeneous catalyst

One-pot conversion of non-edible oil into sustainable biodiesel using novel bifunctional heterogeneous catalyst
This study aims to produce biodiesel from indigenous non-edible feedstock of wild olive seed oil using novel bifunctional xK2O/ZrO2-Bi2O3 catalyst. The designed catalyst was prepared using sol gel-impregnation method. The textural and surface properties of the synthesized catalyst were elucidated using various analytical techniques including EDX, FTIR, XRD, SEM, BET and XPS. The catalyst provided highest biodiesel yield of 95.2 % under the optimized reaction conditions. The successful synthesis of biodiesel was confirmed by GCMS, NMR and FTIR analysis, whereas; the various physiochemical properties were investigated according to the ASTM and EN standards. The designed catalyst showed substantial reproducibility and recyclability up to four times. The mechanism for xK2O/ZrO2-Bi2O3 catalyzed transesterification reaction of WOSO was also proposed. The kinetics studies revealed that the reaction follows pseudo first order and the Ea was calculated to be 32.58 kJ mol−1.
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来源期刊
Renewable Energy
Renewable Energy 工程技术-能源与燃料
CiteScore
18.40
自引率
9.20%
发文量
1955
审稿时长
6.6 months
期刊介绍: Renewable Energy journal is dedicated to advancing knowledge and disseminating insights on various topics and technologies within renewable energy systems and components. Our mission is to support researchers, engineers, economists, manufacturers, NGOs, associations, and societies in staying updated on new developments in their respective fields and applying alternative energy solutions to current practices. As an international, multidisciplinary journal in renewable energy engineering and research, we strive to be a premier peer-reviewed platform and a trusted source of original research and reviews in the field of renewable energy. Join us in our endeavor to drive innovation and progress in sustainable energy solutions.
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