Long Ren , Jing Huang , Xiaoze Wang , Shaowen Yang , Chunhai Yang , Chengfeng Zhao , Lidong Wang , Wenzhou Mei , Mingguo Deng , Yunman Zhou
{"title":"斑岩-矽卡岩型金铜矿矿体分布的岩浆控制:中国西南三江成矿带北雅矿床案例研究","authors":"Long Ren , Jing Huang , Xiaoze Wang , Shaowen Yang , Chunhai Yang , Chengfeng Zhao , Lidong Wang , Wenzhou Mei , Mingguo Deng , Yunman Zhou","doi":"10.1016/j.oregeorev.2024.106350","DOIUrl":null,"url":null,"abstract":"<div><div>The giant Beiya porphyry–skarn-type gold (Au)–copper (Cu) deposit in the Sanjiang domain is marked by the presence of majority of the ore bodies in the wall rock, which is distinct from the fact that the worldwide porphyry–skarn Cu–Au deposits develop abundant Cu–Au ore bodies within ore-forming porphyries; however, the formation mechanism of this peculiar phenomenon remains to be investigated. Here, we take the contemporaneous ore-forming porphyry and postmineralization lamprophyre in the Beiya ore district as object of study and gather new and early data of chronology, mineralogy and geochemistry to elucidate the aforementioned issue. The ore-forming quartz syenite porphyry has been dated at 35.8–36.9 Ma, slightly earlier than the lamprophyre (ca. 34.9 Ma). The lamprophyre has high Ni (55.7–187 ppm), Cr (137–459 ppm), Sr (286–1012 ppm), and Ba (964–2228 ppm) contents; high Ba/La (16.6–33.2) ratio; low Hf/Sm (0.66–1.27) and Zr/Nb (14.9–22.3) ratios; and enriched Sr–Nd isotopes (0.7059–0.7080 and −1.30–4.95, respectively), indicating its origin in an enriched mantle metasomatized by pelagic sediment-related slab fluids. The trace and platinum-group elemental characteristics further demonstrate that the lamprophyre underwent crystal fractionation and sulfide liquation during magmatic evolution. It is clear that the lamprophyre has low Au and Cu concentrations owing to sulfide liquation; therefore, it is unlikely that the ore-forming porphyry evolved from a mantle-derived magma. The quartz syenite porphyry has enriched Sr (0.7067–0.7092), Nd (−2.40 to −6.00), and Hf (−7.40 to 4.90) isotopes, which are similar to the Neoproterozoic crustal materials with high Au (6–16 ppb) and Cu (383–445 ppm) abundances; therefore, we infer that the ore-forming porphyry stemmed from melting of the Neoproterozoic juvenile lower crust. Furthermore, the whole-rock data combined with <em>in situ</em> analysis of zircon and magnetite indicated that the quartz syenite porphyry underwent mafic magma replenishment and crystal fractionation during its evolution. Thus, we can infer that the lower-crustal remelting related to the intracontinental orogenic environment and subsequent biotite fractionation resulted in the lack of mafic minerals for the Beiya ore-forming porphyry, distinct from the worldwide porphyry–skarn Au–Cu deposits that are sourced from enriched mantle wedge and develop a large number of amphiboles and biotites in the ore-forming porphyries. Because of this petrogenetic model, the oxidation–reduction reaction in a porphyry ore-forming system, which is expressed as Fe<sup>2+</sup> in the magma being oxidized to Fe<sup>3+</sup> along with SO<sub>4</sub><sup>2−</sup> being reduced to S<sup>2−</sup>, could only occur in the surrounding rock at the top of the exocontact zone of the ore-forming porphyry via the upward migration of Fe<sup>2+</sup> in the forms of gas phase, thus providing abundant S<sup>2−</sup> for the formation of Au–Cu ore bodies. This peculiar magmatic–metallogenic mechanism also highlights prospecting direction of the Beiya deposit in the future.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"175 ","pages":"Article 106350"},"PeriodicalIF":3.2000,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magmatic control on orebody distribution of porphyry-skarn gold-copper deposit: A case study of Beiya deposit from Sanjiang metallogenic belt in the southwest China\",\"authors\":\"Long Ren , Jing Huang , Xiaoze Wang , Shaowen Yang , Chunhai Yang , Chengfeng Zhao , Lidong Wang , Wenzhou Mei , Mingguo Deng , Yunman Zhou\",\"doi\":\"10.1016/j.oregeorev.2024.106350\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The giant Beiya porphyry–skarn-type gold (Au)–copper (Cu) deposit in the Sanjiang domain is marked by the presence of majority of the ore bodies in the wall rock, which is distinct from the fact that the worldwide porphyry–skarn Cu–Au deposits develop abundant Cu–Au ore bodies within ore-forming porphyries; however, the formation mechanism of this peculiar phenomenon remains to be investigated. Here, we take the contemporaneous ore-forming porphyry and postmineralization lamprophyre in the Beiya ore district as object of study and gather new and early data of chronology, mineralogy and geochemistry to elucidate the aforementioned issue. The ore-forming quartz syenite porphyry has been dated at 35.8–36.9 Ma, slightly earlier than the lamprophyre (ca. 34.9 Ma). The lamprophyre has high Ni (55.7–187 ppm), Cr (137–459 ppm), Sr (286–1012 ppm), and Ba (964–2228 ppm) contents; high Ba/La (16.6–33.2) ratio; low Hf/Sm (0.66–1.27) and Zr/Nb (14.9–22.3) ratios; and enriched Sr–Nd isotopes (0.7059–0.7080 and −1.30–4.95, respectively), indicating its origin in an enriched mantle metasomatized by pelagic sediment-related slab fluids. The trace and platinum-group elemental characteristics further demonstrate that the lamprophyre underwent crystal fractionation and sulfide liquation during magmatic evolution. It is clear that the lamprophyre has low Au and Cu concentrations owing to sulfide liquation; therefore, it is unlikely that the ore-forming porphyry evolved from a mantle-derived magma. The quartz syenite porphyry has enriched Sr (0.7067–0.7092), Nd (−2.40 to −6.00), and Hf (−7.40 to 4.90) isotopes, which are similar to the Neoproterozoic crustal materials with high Au (6–16 ppb) and Cu (383–445 ppm) abundances; therefore, we infer that the ore-forming porphyry stemmed from melting of the Neoproterozoic juvenile lower crust. Furthermore, the whole-rock data combined with <em>in situ</em> analysis of zircon and magnetite indicated that the quartz syenite porphyry underwent mafic magma replenishment and crystal fractionation during its evolution. Thus, we can infer that the lower-crustal remelting related to the intracontinental orogenic environment and subsequent biotite fractionation resulted in the lack of mafic minerals for the Beiya ore-forming porphyry, distinct from the worldwide porphyry–skarn Au–Cu deposits that are sourced from enriched mantle wedge and develop a large number of amphiboles and biotites in the ore-forming porphyries. Because of this petrogenetic model, the oxidation–reduction reaction in a porphyry ore-forming system, which is expressed as Fe<sup>2+</sup> in the magma being oxidized to Fe<sup>3+</sup> along with SO<sub>4</sub><sup>2−</sup> being reduced to S<sup>2−</sup>, could only occur in the surrounding rock at the top of the exocontact zone of the ore-forming porphyry via the upward migration of Fe<sup>2+</sup> in the forms of gas phase, thus providing abundant S<sup>2−</sup> for the formation of Au–Cu ore bodies. This peculiar magmatic–metallogenic mechanism also highlights prospecting direction of the Beiya deposit in the future.</div></div>\",\"PeriodicalId\":19644,\"journal\":{\"name\":\"Ore Geology Reviews\",\"volume\":\"175 \",\"pages\":\"Article 106350\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-11-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ore Geology Reviews\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169136824004839\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ore Geology Reviews","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169136824004839","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOLOGY","Score":null,"Total":0}
Magmatic control on orebody distribution of porphyry-skarn gold-copper deposit: A case study of Beiya deposit from Sanjiang metallogenic belt in the southwest China
The giant Beiya porphyry–skarn-type gold (Au)–copper (Cu) deposit in the Sanjiang domain is marked by the presence of majority of the ore bodies in the wall rock, which is distinct from the fact that the worldwide porphyry–skarn Cu–Au deposits develop abundant Cu–Au ore bodies within ore-forming porphyries; however, the formation mechanism of this peculiar phenomenon remains to be investigated. Here, we take the contemporaneous ore-forming porphyry and postmineralization lamprophyre in the Beiya ore district as object of study and gather new and early data of chronology, mineralogy and geochemistry to elucidate the aforementioned issue. The ore-forming quartz syenite porphyry has been dated at 35.8–36.9 Ma, slightly earlier than the lamprophyre (ca. 34.9 Ma). The lamprophyre has high Ni (55.7–187 ppm), Cr (137–459 ppm), Sr (286–1012 ppm), and Ba (964–2228 ppm) contents; high Ba/La (16.6–33.2) ratio; low Hf/Sm (0.66–1.27) and Zr/Nb (14.9–22.3) ratios; and enriched Sr–Nd isotopes (0.7059–0.7080 and −1.30–4.95, respectively), indicating its origin in an enriched mantle metasomatized by pelagic sediment-related slab fluids. The trace and platinum-group elemental characteristics further demonstrate that the lamprophyre underwent crystal fractionation and sulfide liquation during magmatic evolution. It is clear that the lamprophyre has low Au and Cu concentrations owing to sulfide liquation; therefore, it is unlikely that the ore-forming porphyry evolved from a mantle-derived magma. The quartz syenite porphyry has enriched Sr (0.7067–0.7092), Nd (−2.40 to −6.00), and Hf (−7.40 to 4.90) isotopes, which are similar to the Neoproterozoic crustal materials with high Au (6–16 ppb) and Cu (383–445 ppm) abundances; therefore, we infer that the ore-forming porphyry stemmed from melting of the Neoproterozoic juvenile lower crust. Furthermore, the whole-rock data combined with in situ analysis of zircon and magnetite indicated that the quartz syenite porphyry underwent mafic magma replenishment and crystal fractionation during its evolution. Thus, we can infer that the lower-crustal remelting related to the intracontinental orogenic environment and subsequent biotite fractionation resulted in the lack of mafic minerals for the Beiya ore-forming porphyry, distinct from the worldwide porphyry–skarn Au–Cu deposits that are sourced from enriched mantle wedge and develop a large number of amphiboles and biotites in the ore-forming porphyries. Because of this petrogenetic model, the oxidation–reduction reaction in a porphyry ore-forming system, which is expressed as Fe2+ in the magma being oxidized to Fe3+ along with SO42− being reduced to S2−, could only occur in the surrounding rock at the top of the exocontact zone of the ore-forming porphyry via the upward migration of Fe2+ in the forms of gas phase, thus providing abundant S2− for the formation of Au–Cu ore bodies. This peculiar magmatic–metallogenic mechanism also highlights prospecting direction of the Beiya deposit in the future.
期刊介绍:
Ore Geology Reviews aims to familiarize all earth scientists with recent advances in a number of interconnected disciplines related to the study of, and search for, ore deposits. The reviews range from brief to longer contributions, but the journal preferentially publishes manuscripts that fill the niche between the commonly shorter journal articles and the comprehensive book coverages, and thus has a special appeal to many authors and readers.