用于提高吸附式冷却器性能的废物衍生碳多孔材料:迈向循环经济的一步

IF 6.1 2区 工程技术 Q2 ENERGY & FUELS
Agata Mlonka-Mędrala , Katarzyna Jagodzińska , Tomasz Bujok , Wojciech Kalawa , Tong Han , Karol Sztekler , Wojciech Nowak , Łukasz Mika
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引用次数: 0

摘要

在本研究中,对商用活性碳和从废物中提取的新型多孔碳材料进行了全面检查,以评估它们在由废热驱动的吸附冷却器中作为床层材料的潜力。研究的重点是合成和分析两种不同废物来源的吸附剂:木质素和挖掘出的废物,旨在扩大废物衍生材料的可持续应用。研究人员采用汞侵入孔隙模拟法、低温气体吸附法和甲醇动态蒸汽吸附测量法对吸附特性进行了全面分析。这些技术详细揭示了材料的微孔结构和表面积,活性炭的微孔结构和表面积在 500 到 2000 m2/g 之间。值得注意的是,木质素衍生的磁性生物炭在 30 °C 的操作条件下表现出了异常发达的表面积和卓越的吸附特性,在 P/Po 值为 100 % 时的相对吸附率达到 59.89 %,比市面上的活性炭高出 70 %。这种材料的性能突显了其作为吸附式冷却器中高效吸附剂的潜力,超过了许多市面上的选择。然而,从挖掘出的废弃物中获得的炭具有灰分和重金属含量高(786 毫克/千克铅和 127 毫克/千克锌)的局限性,这对其在活性炭合成中的应用提出了挑战。本研究通过探索在吸附冷却中利用源自废物的多孔碳材料的创新途径,弥补了这一重要的知识空白,从而有助于为热驱动冷却应用开发可持续的、基于废物的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Waste-Derived carbon porous materials for enhanced performance in adsorption chillers: A Step toward a circular economy
In this study, a comprehensive examination of commercial activated carbons and novel porous carbon materials derived from waste was conducted to evaluate their potential as bed materials in adsorption chillers driven by waste heat. The research uniquely focuses on synthesizing and analyzing sorbents from two distinct waste sources: lignin and excavated waste, aiming to expand the sustainable application of waste-derived materials. A thorough characterisation of the sorption properties was performed using mercury intrusion porosimetry, low-temperature gas adsorption, and dynamic vapour sorption measurements with methanol. These techniques provided detailed insights into the microporous structure and surface areas of the materials, ranging from 500 to 2000 m2/g for the activated carbons. Notably, the lignin-derived magnetic biochar demonstrated an exceptionally well-developed surface area and superior sorption properties at operational conditions of 30 °C, reaching relative adsorption of 59.89 % at P/Po of 100 %—up to 70 % higher than that of commercially available activated carbons. This material’s performance highlights its potential as a high-efficiency adsorbent in adsorption chillers, surpassing many commercially available options. However, the char obtained from excavated waste exhibited limitations due to high ash and heavy metal content (786 mg/kg Pb and 127 mg/kg Zn), suggesting challenges for its use in activated carbon synthesis. This study bridges a critical knowledge gap by exploring innovative pathways for utilizing waste-derived porous carbon materials in adsorption cooling, thus contributing to the development of sustainable, waste-based solutions for heat-driven cooling applications.
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来源期刊
Applied Thermal Engineering
Applied Thermal Engineering 工程技术-工程:机械
CiteScore
11.30
自引率
15.60%
发文量
1474
审稿时长
57 days
期刊介绍: Applied Thermal Engineering disseminates novel research related to the design, development and demonstration of components, devices, equipment, technologies and systems involving thermal processes for the production, storage, utilization and conservation of energy, with a focus on engineering application. The journal publishes high-quality and high-impact Original Research Articles, Review Articles, Short Communications and Letters to the Editor on cutting-edge innovations in research, and recent advances or issues of interest to the thermal engineering community.
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