Zhipeng Wang , Zhao Shen , Yang Liu , Yahuan Zhao , Qingchun Zhu , Yiwen Chen , Jingya Wang , Yangxin Li , Sergio Lozano-Perez , Xiaoqin Zeng
{"title":"LPSO 相对不锈钢 Mg-Y-Al 合金高温氧化的影响","authors":"Zhipeng Wang , Zhao Shen , Yang Liu , Yahuan Zhao , Qingchun Zhu , Yiwen Chen , Jingya Wang , Yangxin Li , Sergio Lozano-Perez , Xiaoqin Zeng","doi":"10.1016/j.jma.2024.07.009","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, we investigated the oxidation of the Mg-11Y-1Al alloy at 500 °C in an Ar-20%O<sub>2</sub> environment. Multiscale analysis showed the network-like long-period stacking ordered (LPSO) phase transformed into needle-like LPSO and polygonal Mg<sub>24</sub>Y<sub>5</sub> phases, leading to the formation of a high-dense network of needle-like oxides at the oxidation front. These oxides grew laterally along the oxide/matrix interfaces, forming a thicker, continuous scale that effectively blocked elemental diffusion. Hence, the preferential oxidation along the needle-like LPSO is believed to accelerate the formation of a thicker and continuous oxide scale, further improving the oxidation resistance of the Mg-11Y-1Al alloy.</div></div>","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"12 10","pages":"Pages 4045-4052"},"PeriodicalIF":15.8000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The effect of LPSO phase on the high-temperature oxidation of a stainless Mg-Y-Al alloy\",\"authors\":\"Zhipeng Wang , Zhao Shen , Yang Liu , Yahuan Zhao , Qingchun Zhu , Yiwen Chen , Jingya Wang , Yangxin Li , Sergio Lozano-Perez , Xiaoqin Zeng\",\"doi\":\"10.1016/j.jma.2024.07.009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, we investigated the oxidation of the Mg-11Y-1Al alloy at 500 °C in an Ar-20%O<sub>2</sub> environment. Multiscale analysis showed the network-like long-period stacking ordered (LPSO) phase transformed into needle-like LPSO and polygonal Mg<sub>24</sub>Y<sub>5</sub> phases, leading to the formation of a high-dense network of needle-like oxides at the oxidation front. These oxides grew laterally along the oxide/matrix interfaces, forming a thicker, continuous scale that effectively blocked elemental diffusion. Hence, the preferential oxidation along the needle-like LPSO is believed to accelerate the formation of a thicker and continuous oxide scale, further improving the oxidation resistance of the Mg-11Y-1Al alloy.</div></div>\",\"PeriodicalId\":16214,\"journal\":{\"name\":\"Journal of Magnesium and Alloys\",\"volume\":\"12 10\",\"pages\":\"Pages 4045-4052\"},\"PeriodicalIF\":15.8000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Magnesium and Alloys\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2213956724002482\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnesium and Alloys","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2213956724002482","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
The effect of LPSO phase on the high-temperature oxidation of a stainless Mg-Y-Al alloy
In this study, we investigated the oxidation of the Mg-11Y-1Al alloy at 500 °C in an Ar-20%O2 environment. Multiscale analysis showed the network-like long-period stacking ordered (LPSO) phase transformed into needle-like LPSO and polygonal Mg24Y5 phases, leading to the formation of a high-dense network of needle-like oxides at the oxidation front. These oxides grew laterally along the oxide/matrix interfaces, forming a thicker, continuous scale that effectively blocked elemental diffusion. Hence, the preferential oxidation along the needle-like LPSO is believed to accelerate the formation of a thicker and continuous oxide scale, further improving the oxidation resistance of the Mg-11Y-1Al alloy.
期刊介绍:
The Journal of Magnesium and Alloys serves as a global platform for both theoretical and experimental studies in magnesium science and engineering. It welcomes submissions investigating various scientific and engineering factors impacting the metallurgy, processing, microstructure, properties, and applications of magnesium and alloys. The journal covers all aspects of magnesium and alloy research, including raw materials, alloy casting, extrusion and deformation, corrosion and surface treatment, joining and machining, simulation and modeling, microstructure evolution and mechanical properties, new alloy development, magnesium-based composites, bio-materials and energy materials, applications, and recycling.