一步选择性合成双、三融合手性硼硼烷衍生物。

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-11-22 DOI:10.1039/d4cc04433a

Josina L Bohlen, Nele Wieprecht, Merle Arrowsmith, Alena Häfner, Marco Neder, Holger Braunschweig

引用次数: 0

摘要

手性 3a,6a-二氢硼并[3,2-b]硼烷通过 1-硼基-2-(二卤代硼酰)炔中间体的复杂重排反应，以非对映选择性步骤从正(二卤代硼酰)炔与锡烯衍生物的反应中获得。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives.

Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.