通过软硬交错形成模式获得高接触应力下超长磨损寿命的氧化石墨烯薄膜

IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Li Chen, Hang Zhu, Gang Wu, Bo Mu, Yaqian Liu, Xingkai Zhang, Changning Bai
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引用次数: 0

摘要

作为石墨烯衍生物的典型代表,氧化石墨烯(GO)在微/纳米电子机械系统中展现出了无与伦比的潜力,明显提高了移动机械设备的效率和精度。然而,石墨烯氧化物一直存在磨损寿命不足的问题,尤其是在高接触应力条件下,其后续改进仍是一项挑战。本文利用带正电荷的聚(丙烯酰胺-二烯丙基二甲基氯化铵)(品牌:PQ-7)和带负电荷的 GO 之间的强电荷相互作用,将二者交替旋涂在以 3- 氨基丙基三乙氧基硅烷为粘合剂层改性的硅基底上,形成(GO/PQ-7)n 复合多层膜。在 4N 的高负载下,(GO/PQ-7)5 多层膜的使用寿命超过 27000 秒,是 GO 膜的 20 倍。优异的摩擦性能归功于(GO/PQ-7)n 复合多层膜的独特结构,即由刚性 GO 和柔性聚合物组成的弹性三维叠层。这种软硬交错的形成膜不仅能很好地整合界面,还能有效防止裂纹扩展。它还充分利用了软层可消除应力、硬层可提供承载能力的优势。此外,摩擦诱导部分 GO 向石墨烯的转化可确保滑动界面的低摩擦。这种策略为设计和制造微/纳米电子机械系统和其他微型设备的润滑薄膜提供了一个开放的平台。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Obtaining Ultra-long Wear Lifetime of Graphene Oxide Films Under High Contact Stress Through Soft and Hard Interbeded Formation Mode

As the quintessential representation of graphene derivatives, graphene oxide (GO) has demonstrated unparalleled potential in micro/nano electronic mechanical systems, which visibly enhances the efficiency and accuracy of moving mechanical devices. However, GO has always been subject to the problem of insufficient wear lifetime, and the subsequent improvement is still a challenge, especially under high contact stress. In this paper, making use of the strong charge interactions between positively charged poly(acrylamide-co-diallyldimethylammonium chloride) (Brand: PQ-7) and negatively charged GO, both were alternately spin-coated on the silicon substrates modified by 3-aminopropyltriethoxysilane as an adhesive layer to form (GO/PQ-7)n composite multilayer film. The service life of (GO/PQ-7)5 multilayer film exceeds 27000 s under high load of 4N, which is 20 times longer than that of the GO film. The superior friction performance is ascribed to the distinctive structure of (GO/PQ-7)n composite multilayers, that is, an elastic 3-dimensional stack composed of rigid GO and flexible polymer. This soft and hard interbeded formation film not only integrates the interface well, but also effectively prevents the crack expansion. It also leverages the advantages of soft layers providing stress relief and hard layers providing load-bearing capacity. What's more, friction-induced conversion of partial GO to graphene ensures low friction at the sliding interface. This strategy provides an open platform for the design and fabrication of lubricating films for micro/nano electronic mechanical systems and other microdevices.

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来源期刊
Tribology Letters
Tribology Letters 工程技术-工程:化工
CiteScore
5.30
自引率
9.40%
发文量
116
审稿时长
2.5 months
期刊介绍: Tribology Letters is devoted to the development of the science of tribology and its applications, particularly focusing on publishing high-quality papers at the forefront of tribological science and that address the fundamentals of friction, lubrication, wear, or adhesion. The journal facilitates communication and exchange of seminal ideas among thousands of practitioners who are engaged worldwide in the pursuit of tribology-based science and technology.
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