Azhan Ahmad, Monali Priyadarshini, Shraddha Yadav, Makarand M. Ghangrekar and Rao Y. Surampalli
{"title":"利用可持续生物-电-芬顿和共沉淀营养物回收技术,污泥衍生新型 Fe3O4-MgO@C 复合材料用于消除废水中的四环素:变废物为资源的策略†。","authors":"Azhan Ahmad, Monali Priyadarshini, Shraddha Yadav, Makarand M. Ghangrekar and Rao Y. Surampalli","doi":"10.1039/D4EW00684D","DOIUrl":null,"url":null,"abstract":"<p >Developing efficient Fenton catalysts for the remediation of emerging pollutants is one of the challenges for researchers. Herein, a novel cathode catalyst <em>via</em> the utilization of waste electro-coagulated (ECO) sludge was synthesized for the efficient abatement of tetracycline (TC) through the bio-electro-Fenton (BEF) process. The carbon-felt-coated heterogeneous catalyst (Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C) resulted in more than 96.7 ± 2.2% removal of 10 mg L<small><sup>−1</sup></small> of TC during 420 min of operating time following pseudo-first-order kinetics at neutral pH. Moreover, 53.5 ± 2.5% mineralization in terms of total organic carbon removal was obtained for real municipal wastewater during the BEF treatment. Radical experimentation displayed ˙OH as the dominant oxidative species for TC degradation. Besides, the maximum power density achieved by Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C-BEF was 114.5 ± 4.5 mW m<small><sup>−2</sup></small>, which was 2.6-times more than BEF operated without any catalyst (44.2 ± 2.7 mW m<small><sup>−2</sup></small>). The co-precipitation in the cathodic chamber of BEF <em>via</em> external addition of Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C (63.6 mg L<small><sup>−1</sup></small>) resulted in 1.20 ± 0.08 g L<small><sup>−1</sup></small> of struvite recovery from synthetic urine. Overall, the sludge-derived catalyst might be beneficial for reducing the economics of future full-scale implementation of the technology, contributing to a circular economy, and fixing the lacunas of ECO technology for sludge management, thereby proposing an effective waste management strategy.</p>","PeriodicalId":75,"journal":{"name":"Environmental Science: Water Research & Technology","volume":" 12","pages":" 3172-3188"},"PeriodicalIF":3.5000,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sludge-derived novel Fe3O4–MgO@C composites for tetracycline abatement from wastewater using sustainable bio-electro-Fenton and nutrient recovery with co-precipitation: a waste-to-resource strategy†\",\"authors\":\"Azhan Ahmad, Monali Priyadarshini, Shraddha Yadav, Makarand M. Ghangrekar and Rao Y. Surampalli\",\"doi\":\"10.1039/D4EW00684D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Developing efficient Fenton catalysts for the remediation of emerging pollutants is one of the challenges for researchers. Herein, a novel cathode catalyst <em>via</em> the utilization of waste electro-coagulated (ECO) sludge was synthesized for the efficient abatement of tetracycline (TC) through the bio-electro-Fenton (BEF) process. The carbon-felt-coated heterogeneous catalyst (Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C) resulted in more than 96.7 ± 2.2% removal of 10 mg L<small><sup>−1</sup></small> of TC during 420 min of operating time following pseudo-first-order kinetics at neutral pH. Moreover, 53.5 ± 2.5% mineralization in terms of total organic carbon removal was obtained for real municipal wastewater during the BEF treatment. Radical experimentation displayed ˙OH as the dominant oxidative species for TC degradation. Besides, the maximum power density achieved by Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C-BEF was 114.5 ± 4.5 mW m<small><sup>−2</sup></small>, which was 2.6-times more than BEF operated without any catalyst (44.2 ± 2.7 mW m<small><sup>−2</sup></small>). The co-precipitation in the cathodic chamber of BEF <em>via</em> external addition of Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>–MgO@C (63.6 mg L<small><sup>−1</sup></small>) resulted in 1.20 ± 0.08 g L<small><sup>−1</sup></small> of struvite recovery from synthetic urine. Overall, the sludge-derived catalyst might be beneficial for reducing the economics of future full-scale implementation of the technology, contributing to a circular economy, and fixing the lacunas of ECO technology for sludge management, thereby proposing an effective waste management strategy.</p>\",\"PeriodicalId\":75,\"journal\":{\"name\":\"Environmental Science: Water Research & Technology\",\"volume\":\" 12\",\"pages\":\" 3172-3188\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-10-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Science: Water Research & Technology\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ew/d4ew00684d\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science: Water Research & Technology","FirstCategoryId":"93","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ew/d4ew00684d","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Sludge-derived novel Fe3O4–MgO@C composites for tetracycline abatement from wastewater using sustainable bio-electro-Fenton and nutrient recovery with co-precipitation: a waste-to-resource strategy†
Developing efficient Fenton catalysts for the remediation of emerging pollutants is one of the challenges for researchers. Herein, a novel cathode catalyst via the utilization of waste electro-coagulated (ECO) sludge was synthesized for the efficient abatement of tetracycline (TC) through the bio-electro-Fenton (BEF) process. The carbon-felt-coated heterogeneous catalyst (Fe3O4–MgO@C) resulted in more than 96.7 ± 2.2% removal of 10 mg L−1 of TC during 420 min of operating time following pseudo-first-order kinetics at neutral pH. Moreover, 53.5 ± 2.5% mineralization in terms of total organic carbon removal was obtained for real municipal wastewater during the BEF treatment. Radical experimentation displayed ˙OH as the dominant oxidative species for TC degradation. Besides, the maximum power density achieved by Fe3O4–MgO@C-BEF was 114.5 ± 4.5 mW m−2, which was 2.6-times more than BEF operated without any catalyst (44.2 ± 2.7 mW m−2). The co-precipitation in the cathodic chamber of BEF via external addition of Fe3O4–MgO@C (63.6 mg L−1) resulted in 1.20 ± 0.08 g L−1 of struvite recovery from synthetic urine. Overall, the sludge-derived catalyst might be beneficial for reducing the economics of future full-scale implementation of the technology, contributing to a circular economy, and fixing the lacunas of ECO technology for sludge management, thereby proposing an effective waste management strategy.
期刊介绍:
Environmental Science: Water Research & Technology seeks to showcase high quality research about fundamental science, innovative technologies, and management practices that promote sustainable water.