Jitesh Pani, Priyanka Chaudhary, Hitesh Borkar and Meng-Fang Lin
{"title":"在用于储能应用的磺化 Ti3C2Tx MXene 中战略性地插层 AB2O4 包晶氧化物,以协同增强氧化还原活性","authors":"Jitesh Pani, Priyanka Chaudhary, Hitesh Borkar and Meng-Fang Lin","doi":"10.1039/D4TA05816J","DOIUrl":null,"url":null,"abstract":"<p >Flexible supercapacitors have emerged as efficient and fast energy storage devices for new generation electronics. Two-dimensional (2D) transition metal carbides (MXene) have garnered attention as supercapacitor electrodes owing to their conductive layered sheets and the tunability of their surface functional groups. In the present work, the Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small> MXene surface was sulphonated using dimethyl sulfoxide (DMSO) and intercalated with AB<small><sub>2</sub></small>O<small><sub>4</sub></small> (A = Co and Ni; B = <img>Fe) perovskite nanoparticle (NPs). The sulphonated MXene (TMS) was processed using a sonication method in DMSO solvent to enhance the surface area and redox active sites for electrolyte (0.1 M H<small><sub>2</sub></small>SO<small><sub>4</sub></small>) interaction. The redox dominated enhancement in specific capacitance was observed in 3 wt% CoFe<small><sub>2</sub></small>O<small><sub>4</sub></small> (CFO)-intercalated TMS (3CTMS) and 3 wt% NiFe<small><sub>2</sub></small>O<small><sub>4</sub></small> (NFO)-intercalated TMS (3NTMS), as confirmed by Electrochemical Impedance Spectroscopy (EIS) and Dunn's method analysis. The specific capacitance of 3CTMS was found to be 593.81 F g<small><sup>−1</sup></small> at 5 mV s<small><sup>−1</sup></small>, with an excellent cyclic stability of 81.75% after 10 000 cycles. A flexible symmetric supercapacitor fabricated with 3CTMS showed an energy density of 4.177 W h kg<small><sup>−1</sup></small> and a power density of 512.17 W kg<small><sup>−1</sup></small>. The flexible supercapacitor has been utilized in real time applications by charging and discharging to power 5 Light-Emitting Diodes (LEDs) with different forward voltages.</p>","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":" 6","pages":" 4107-4118"},"PeriodicalIF":10.7000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Strategic intercalation of AB2O4 perovskite oxides for synergetic enhanced redox activity in sulphonated Ti3C2Tx MXene for energy storage applications†\",\"authors\":\"Jitesh Pani, Priyanka Chaudhary, Hitesh Borkar and Meng-Fang Lin\",\"doi\":\"10.1039/D4TA05816J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Flexible supercapacitors have emerged as efficient and fast energy storage devices for new generation electronics. Two-dimensional (2D) transition metal carbides (MXene) have garnered attention as supercapacitor electrodes owing to their conductive layered sheets and the tunability of their surface functional groups. In the present work, the Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small> MXene surface was sulphonated using dimethyl sulfoxide (DMSO) and intercalated with AB<small><sub>2</sub></small>O<small><sub>4</sub></small> (A = Co and Ni; B = <img>Fe) perovskite nanoparticle (NPs). The sulphonated MXene (TMS) was processed using a sonication method in DMSO solvent to enhance the surface area and redox active sites for electrolyte (0.1 M H<small><sub>2</sub></small>SO<small><sub>4</sub></small>) interaction. The redox dominated enhancement in specific capacitance was observed in 3 wt% CoFe<small><sub>2</sub></small>O<small><sub>4</sub></small> (CFO)-intercalated TMS (3CTMS) and 3 wt% NiFe<small><sub>2</sub></small>O<small><sub>4</sub></small> (NFO)-intercalated TMS (3NTMS), as confirmed by Electrochemical Impedance Spectroscopy (EIS) and Dunn's method analysis. The specific capacitance of 3CTMS was found to be 593.81 F g<small><sup>−1</sup></small> at 5 mV s<small><sup>−1</sup></small>, with an excellent cyclic stability of 81.75% after 10 000 cycles. A flexible symmetric supercapacitor fabricated with 3CTMS showed an energy density of 4.177 W h kg<small><sup>−1</sup></small> and a power density of 512.17 W kg<small><sup>−1</sup></small>. The flexible supercapacitor has been utilized in real time applications by charging and discharging to power 5 Light-Emitting Diodes (LEDs) with different forward voltages.</p>\",\"PeriodicalId\":82,\"journal\":{\"name\":\"Journal of Materials Chemistry A\",\"volume\":\" 6\",\"pages\":\" 4107-4118\"},\"PeriodicalIF\":10.7000,\"publicationDate\":\"2024-11-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry A\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ta/d4ta05816j\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ta/d4ta05816j","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Strategic intercalation of AB2O4 perovskite oxides for synergetic enhanced redox activity in sulphonated Ti3C2Tx MXene for energy storage applications†
Flexible supercapacitors have emerged as efficient and fast energy storage devices for new generation electronics. Two-dimensional (2D) transition metal carbides (MXene) have garnered attention as supercapacitor electrodes owing to their conductive layered sheets and the tunability of their surface functional groups. In the present work, the Ti3C2Tx MXene surface was sulphonated using dimethyl sulfoxide (DMSO) and intercalated with AB2O4 (A = Co and Ni; B = Fe) perovskite nanoparticle (NPs). The sulphonated MXene (TMS) was processed using a sonication method in DMSO solvent to enhance the surface area and redox active sites for electrolyte (0.1 M H2SO4) interaction. The redox dominated enhancement in specific capacitance was observed in 3 wt% CoFe2O4 (CFO)-intercalated TMS (3CTMS) and 3 wt% NiFe2O4 (NFO)-intercalated TMS (3NTMS), as confirmed by Electrochemical Impedance Spectroscopy (EIS) and Dunn's method analysis. The specific capacitance of 3CTMS was found to be 593.81 F g−1 at 5 mV s−1, with an excellent cyclic stability of 81.75% after 10 000 cycles. A flexible symmetric supercapacitor fabricated with 3CTMS showed an energy density of 4.177 W h kg−1 and a power density of 512.17 W kg−1. The flexible supercapacitor has been utilized in real time applications by charging and discharging to power 5 Light-Emitting Diodes (LEDs) with different forward voltages.
期刊介绍:
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.