超快检测苦味酸和盐酸蒸汽传感的荧光共价有机笼。

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2024-11-20 DOI:10.1002/asia.202400912

Amit Kumar Mahto, Sahadev Barik, Jaya Prakash Madda, Moloy Sarkar

{"title":"超快检测苦味酸和盐酸蒸汽传感的荧光共价有机笼。","authors":"Amit Kumar Mahto, Sahadev Barik, Jaya Prakash Madda, Moloy Sarkar","doi":"10.1002/asia.202400912","DOIUrl":null,"url":null,"abstract":"Covalent organic cages (COCs) have recently gained massive attention owing to their solution processability and structural flexibility. Herein, we report an amine-linked fluorescent COC (COC2) synthesized by adopting dynamic covalent imine chemistry followed by imine bond reduction and characterized with different spectroscopic techniques. The COC2 was utilized for highly sensitive and selective detection of picric acid at the nanomolar level. The fluorescence quenching efficiency of PA towards the COC2 is 98.6%, with a detection limit of 2.7 nM. PA sensing with the COC2, coated on a TLC plate and paper strip, exhibited an outstanding fluorescence quenching property. Furthermore, the COC2 unveiled solid-state acidochromism upon exposure to HCl acid fumes and was transferred back to the original form on exposure to NH3 vapours.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202400912"},"PeriodicalIF":3.5000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Fluorescent Covalent Organic Cage for Ultrafast Detection of Picric Acid and HCl Vapor Sensing.\",\"authors\":\"Amit Kumar Mahto, Sahadev Barik, Jaya Prakash Madda, Moloy Sarkar\",\"doi\":\"10.1002/asia.202400912\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Covalent organic cages (COCs) have recently gained massive attention owing to their solution processability and structural flexibility. Herein, we report an amine-linked fluorescent COC (COC2) synthesized by adopting dynamic covalent imine chemistry followed by imine bond reduction and characterized with different spectroscopic techniques. The COC2 was utilized for highly sensitive and selective detection of picric acid at the nanomolar level. The fluorescence quenching efficiency of PA towards the COC2 is 98.6%, with a detection limit of 2.7 nM. PA sensing with the COC2, coated on a TLC plate and paper strip, exhibited an outstanding fluorescence quenching property. Furthermore, the COC2 unveiled solid-state acidochromism upon exposure to HCl acid fumes and was transferred back to the original form on exposure to NH3 vapours.\",\"PeriodicalId\":145,\"journal\":{\"name\":\"Chemistry - An Asian Journal\",\"volume\":\" \",\"pages\":\"e202400912\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-11-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - An Asian Journal\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1002/asia.202400912\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1002/asia.202400912","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

共价有机笼（COC）因其溶液可加工性和结构灵活性而在近期受到广泛关注。在此，我们报告了一种胺连接的荧光 COC（COC2），该 COC2 是通过动态共价亚胺化学反应，然后通过亚胺键还原合成的，并利用不同的光谱技术对其进行了表征。COC2 被用于纳摩尔级的高灵敏度和选择性苦味酸检测。PA 对 COC2 的荧光淬灭效率为 98.6%，检测限为 2.7 nM。用涂布在 TLC 板和纸条上的 COC2 对 PA 进行传感，显示出出色的荧光淬灭特性。此外，COC2 在暴露于 HCl 酸烟雾时会呈现固态酸色，而在暴露于 NH3 蒸汽时又会变回原来的形式。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

A Fluorescent Covalent Organic Cage for Ultrafast Detection of Picric Acid and HCl Vapor Sensing.

Covalent organic cages (COCs) have recently gained massive attention owing to their solution processability and structural flexibility. Herein, we report an amine-linked fluorescent COC (COC2) synthesized by adopting dynamic covalent imine chemistry followed by imine bond reduction and characterized with different spectroscopic techniques. The COC2 was utilized for highly sensitive and selective detection of picric acid at the nanomolar level. The fluorescence quenching efficiency of PA towards the COC2 is 98.6%, with a detection limit of 2.7 nM. PA sensing with the COC2, coated on a TLC plate and paper strip, exhibited an outstanding fluorescence quenching property. Furthermore, the COC2 unveiled solid-state acidochromism upon exposure to HCl acid fumes and was transferred back to the original form on exposure to NH3 vapours.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).