Norah A. M. Alsaif, Hanan Al-Ghamdi, Z. Y. Khattari, Nada Alfryyan, A. M. Abdelghany, A. S. Abouhaswa, Y. S. Rammah
{"title":"高密度铅硼酸镉玻璃:制造、物理性质以及用于γ射线和中子屏蔽的能力","authors":"Norah A. M. Alsaif, Hanan Al-Ghamdi, Z. Y. Khattari, Nada Alfryyan, A. M. Abdelghany, A. S. Abouhaswa, Y. S. Rammah","doi":"10.1007/s11082-024-06751-7","DOIUrl":null,"url":null,"abstract":"<div><p>High dense cadmium lead-borate glasses with nominal compositions of (75-X)B<sub>2</sub>O<sub>3</sub>-XPbO-5Na<sub>2</sub>O-10CdO-10ZnO: X = 5–20 mol% in steps of 5 were fabricated via the melt quenching technique. The physical features and the capability of applying the prepared glasses as γ-ray and fast neutron shields have been investigated. The density (D<sub>s</sub>) values increased from 4.820 g.cm<sup>−3</sup> to 5.664 g cm<sup>−3</sup> as PbO content increased from 5 to 20 mol% in the glass network. The polaron radius (r<sub>p</sub>) increased, while the field strength (F) reduced as PbO content increased. The boron ion concentration (N<sub>B</sub>) of the investigated glasses decreased from 2.231 × 10<sup>22</sup> (ions.cm<sup>−3</sup>) to 1.503 × 10<sup>22</sup> (ions/cm<sup>3</sup>). The inter-ionic distance (r<sub>i</sub>) values increased from 3.551 to 4.051 A<sup>o</sup>. Values of the packing density (P<sub>d</sub>) decreased from 0.888 to 0.695. The free volume (V<sub>f</sub>) enhanced from 2.105 to 6.698 g mol<sup>−1</sup> cm<sup>−2</sup>. The sample BPNCZPb-20 possessed the highest exposure (EBF) and energy absorption (EABF) buildup factors values at 1– 40 MFP among all investigated glasses. The half- value layer (HVL<sub>FCS</sub>) and the relaxation length (λ<sub>FCS</sub>) values were the lowest for the BPNCZPb-5 glass sample. Therefore, the sample coded as BPNCZPb-20 can be considered as γ-ray shield, but BPNCZPb-5 glass can be used as a neutron shield.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"56 12","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High dense cadmium lead-borate glasses: fabrication, physical properties and capability for γ-ray and neutron shields\",\"authors\":\"Norah A. M. Alsaif, Hanan Al-Ghamdi, Z. Y. Khattari, Nada Alfryyan, A. M. Abdelghany, A. S. Abouhaswa, Y. S. Rammah\",\"doi\":\"10.1007/s11082-024-06751-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>High dense cadmium lead-borate glasses with nominal compositions of (75-X)B<sub>2</sub>O<sub>3</sub>-XPbO-5Na<sub>2</sub>O-10CdO-10ZnO: X = 5–20 mol% in steps of 5 were fabricated via the melt quenching technique. The physical features and the capability of applying the prepared glasses as γ-ray and fast neutron shields have been investigated. The density (D<sub>s</sub>) values increased from 4.820 g.cm<sup>−3</sup> to 5.664 g cm<sup>−3</sup> as PbO content increased from 5 to 20 mol% in the glass network. The polaron radius (r<sub>p</sub>) increased, while the field strength (F) reduced as PbO content increased. The boron ion concentration (N<sub>B</sub>) of the investigated glasses decreased from 2.231 × 10<sup>22</sup> (ions.cm<sup>−3</sup>) to 1.503 × 10<sup>22</sup> (ions/cm<sup>3</sup>). The inter-ionic distance (r<sub>i</sub>) values increased from 3.551 to 4.051 A<sup>o</sup>. Values of the packing density (P<sub>d</sub>) decreased from 0.888 to 0.695. The free volume (V<sub>f</sub>) enhanced from 2.105 to 6.698 g mol<sup>−1</sup> cm<sup>−2</sup>. The sample BPNCZPb-20 possessed the highest exposure (EBF) and energy absorption (EABF) buildup factors values at 1– 40 MFP among all investigated glasses. The half- value layer (HVL<sub>FCS</sub>) and the relaxation length (λ<sub>FCS</sub>) values were the lowest for the BPNCZPb-5 glass sample. Therefore, the sample coded as BPNCZPb-20 can be considered as γ-ray shield, but BPNCZPb-5 glass can be used as a neutron shield.</p></div>\",\"PeriodicalId\":720,\"journal\":{\"name\":\"Optical and Quantum Electronics\",\"volume\":\"56 12\",\"pages\":\"\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-11-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical and Quantum Electronics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11082-024-06751-7\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical and Quantum Electronics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11082-024-06751-7","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
High dense cadmium lead-borate glasses: fabrication, physical properties and capability for γ-ray and neutron shields
High dense cadmium lead-borate glasses with nominal compositions of (75-X)B2O3-XPbO-5Na2O-10CdO-10ZnO: X = 5–20 mol% in steps of 5 were fabricated via the melt quenching technique. The physical features and the capability of applying the prepared glasses as γ-ray and fast neutron shields have been investigated. The density (Ds) values increased from 4.820 g.cm−3 to 5.664 g cm−3 as PbO content increased from 5 to 20 mol% in the glass network. The polaron radius (rp) increased, while the field strength (F) reduced as PbO content increased. The boron ion concentration (NB) of the investigated glasses decreased from 2.231 × 1022 (ions.cm−3) to 1.503 × 1022 (ions/cm3). The inter-ionic distance (ri) values increased from 3.551 to 4.051 Ao. Values of the packing density (Pd) decreased from 0.888 to 0.695. The free volume (Vf) enhanced from 2.105 to 6.698 g mol−1 cm−2. The sample BPNCZPb-20 possessed the highest exposure (EBF) and energy absorption (EABF) buildup factors values at 1– 40 MFP among all investigated glasses. The half- value layer (HVLFCS) and the relaxation length (λFCS) values were the lowest for the BPNCZPb-5 glass sample. Therefore, the sample coded as BPNCZPb-20 can be considered as γ-ray shield, but BPNCZPb-5 glass can be used as a neutron shield.
期刊介绍:
Optical and Quantum Electronics provides an international forum for the publication of original research papers, tutorial reviews and letters in such fields as optical physics, optical engineering and optoelectronics. Special issues are published on topics of current interest.
Optical and Quantum Electronics is published monthly. It is concerned with the technology and physics of optical systems, components and devices, i.e., with topics such as: optical fibres; semiconductor lasers and LEDs; light detection and imaging devices; nanophotonics; photonic integration and optoelectronic integrated circuits; silicon photonics; displays; optical communications from devices to systems; materials for photonics (e.g. semiconductors, glasses, graphene); the physics and simulation of optical devices and systems; nanotechnologies in photonics (including engineered nano-structures such as photonic crystals, sub-wavelength photonic structures, metamaterials, and plasmonics); advanced quantum and optoelectronic applications (e.g. quantum computing, memory and communications, quantum sensing and quantum dots); photonic sensors and bio-sensors; Terahertz phenomena; non-linear optics and ultrafast phenomena; green photonics.