黑色磷烯:彻底改变环境、能源和生物医学应用的多功能同素异形体

IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Soumya Ranjan Mishra , Vishal Gadore , Vishwajit Chavda , Subhasree Panda , Saptarshi Roy , Pooja Sahoo , Lipi Pradhan , Harshita Rai , Shyam S. Pandey , Md. Ahmaruzzaman
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引用次数: 0

摘要

黑膦石(BP)是一种令人兴奋的磷的同素异形体,由于其独特的物理化学特性以及在环境、能源和生物领域的众多潜力,引发了广泛的关注。本综述将进一步深入探讨 BP,重点关注其层状结构、不寻常的特征和广泛的应用。文章回顾了 BP 的合成方法,如液体剥离、化学气相沉积和机械剥离,并介绍了对确保 BP 质量至关重要的表征程序。利用从六方晶格原子结构和皱褶层中获得的洞察力,对其各向异性的机械、电气和光学特性进行了研究。在环境方面,由于 BP 对各种污染物(包括染料、药物、杀虫剂、重金属和有机化合物)具有很强的吸附和降解能力,因此具有净化水的潜力。它在环境传感方面的潜力也得到了强调,特别是在检测气体、重金属和污染物方面。在能源应用方面,BP 可用于电池、超级电容器和制氢,其独特的电气和结构特性可提高能量存储和转换效率。英国石油公司通过提供生物兼容性和可定制的给药能力,改善了生物医学应用中的给药系统。此外,还对其生物成像和诊断应用进行了审查,重点关注其光学特性和对比度增强能力。然而,尽管 BP 具有巨大的潜力,但仍然存在严重的障碍。需要解决的问题包括环境下的稳定性、大规模合成的限制以及生物相容性方面的困难,以实现更广泛的实际应用。本文最后探讨了未来的挑战和解决方案,以激发读者的兴趣。总之,BP 是一种灵活的材料,可推动环境、能源和生物应用领域的创新,但要实现其革命性的影响,还需要克服目前的技术、科学和规模限制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Black phosphorene: A versatile allotrope revolutionizing environmental, energy, and biomedical applications

Black phosphorene: A versatile allotrope revolutionizing environmental, energy, and biomedical applications

Black phosphorene: A versatile allotrope revolutionizing environmental, energy, and biomedical applications
Black phosphorene (BP), an exciting allotrope of phosphorus, has sparked widespread attention owing to its unique physicochemical characteristics and numerous potentials in the environmental, energy, and biological sectors. The current review delves further into BP, concentrating on its layered structure, unusual features, and broad applications. Methods of synthesis of BP, such as liquid exfoliation, chemical vapor deposition, and mechanical exfoliation, are reviewed, and characterization procedures critical to ensuring the quality of BP are described. Its anisotropic mechanical, electrical, and optical properties are investigated using insights gained from its hexagonal lattice atomic structure and puckered layers. In environmental contexts, BP shows potential for water purification due to its strong adsorption and degradation capabilities against various contaminants, including dyes, medicines, pesticides, heavy metals, and organic compounds. Its potential in environmental sensing is also emphasized, notably for detecting gasses, heavy metals, and pollutants. Moving on to energy applications, BP is used in batteries, supercapacitors, and hydrogen generation, where its unique electrical and structural properties improve energy storage and conversion efficiency. BP improves medication delivery systems in biomedical applications by providing biocompatibility and customizable delivery capabilities. Furthermore, its biological imaging and diagnostics applications are reviewed, focusing on optical properties and contrast enhancement capabilities. Nonetheless, despite BP's significant potential, serious hurdles persist. Issues including stability under ambient settings, large-scale synthesis limits, and biocompatibility difficulties require resolution for more considerable practical use. The paper concludes by exploring future challenges and solutions to motivate readers. In summary, BP stands as a flexible material prepared to drive innovation in environmental, energy, and biological applications, although attaining its revolutionary influence will depend on overcoming present technological, scientific, and scaling limitations.
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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