利用选择性光溴化-脱溴方法,从低成本乙烯焦油沥青中可控制备高拉伸强度碳纤维用可纺各向同性沥青

IF 4.1 2区 化学 Q2 POLYMER SCIENCE
Ganggang Zhai , Jianguang Guo , Yongsheng Tian , Guanming Yuan , Ye Cong , Baoliu Li , Qin Zhang , Yongting Chen , Xuanke Li , Zhijun Dong
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引用次数: 0

摘要

N-bromosuccinimide (NBS) 对于溴化带有烷基侧链的芳香族化合物具有显著的选择性。本研究利用 NBS 代替液溴,采用选择性光溴化-脱溴方法制备可纺的各向同性沥青,这些沥青来自乙烯焦油沥青(ETP)。然后,利用制备的各向同性沥青,通过熔融纺丝、氧化稳定和随后的碳化过程,制造出各向同性沥青基碳纤维(IPCF)。随着光溴化阶段 NBS 添加量的增加,所得各向同性沥青的软化点、沥青产率、平均分子量和聚合度逐渐增加,而其可纺性先改善后降低。与仅通过热聚合生产的各向同性沥青相比,经过光溴化-脱溴处理的各向同性沥青呈现出一种由亚甲基/亚乙基桥接芳香族单元形成的线性分子结构。这种分子结构提高了其可纺性,显著改善了所生产的 IPCF 的机械性能。在光溴化过程中使用 15 wt% NBS 生产的各向同性沥青具有优异的可纺性,生产出的碳纤维具有出色的机械性能。这些纤维的拉伸强度为 1333 兆帕,杨氏模量为 64 GPa,伸长率为 2.4%。这项研究通过控制沥青前驱体的分子结构,为高附加值利用 ET 提供了一种新方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Controllable preparation of spinnable isotropic pitches for carbon fibers with high tensile strength from low-cost ethylene tar pitch by a selective photobromination–debromination method

Controllable preparation of spinnable isotropic pitches for carbon fibers with high tensile strength from low-cost ethylene tar pitch by a selective photobromination–debromination method

Controllable preparation of spinnable isotropic pitches for carbon fibers with high tensile strength from low-cost ethylene tar pitch by a selective photobromination–debromination method
N-bromosuccinimide (NBS) has notable selectivity for brominating aromatic compounds with alkyl side chains. This study employs NBS in lieu of liquid bromine to prepare spinnable isotropic pitch derived from ethylene tar pitch (ETP) using a selective photobromination-debromination approach. The prepared isotropic pitches were then utilized to fabricate isotropic pitch-based carbon fibers (IPCFs) through a process involving melt spinning, oxidative stabilization, and subsequent carbonization. As the amount of NBS added increases in the photobromination stage, the softening point, pitch yield, average molecular weight, and degree of polymerization of the resulting isotropic pitch gradually increase, whereas its spinnability first improves but then decreases. Compared with the isotropic pitch manufactured through thermal polymerization alone, the isotropic pitch that undergo photobromination–debromination exhibits a more linear molecular structure formed by methylene/ethylidene-bridged aromatic units. This molecular structure enhances its spinnability, significantly improving the mechanical performance of the resulting IPCFs. The isotropic pitch produced with 15 wt% NBS during photobromination demonstrates exceptional spinnability, yielding carbon fibers with excellent mechanical characteristics. These fibers exhibit a tensile strength of 1333 MPa, Young's modulus of 64 GPa, and an elongation property of 2.4 %. This work provides a new method for the high value-added utilization of ET by controlling the molecular structure of the pitch precursor.
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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