从生物质废弃物中提取的 Ni/PiNe 异构催化剂:低负载、无配体的 Suzukii-Miyaura 交叉偶联。

IF 7.5 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
ChemSusChem Pub Date : 2024-11-19 DOI:10.1002/cssc.202402011
Federica Valentini, Shaomin Chen, Giulia Brufani, Yanlong Gu, Luigi Vaccaro
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引用次数: 0

摘要

采用资源循环利用策略,从松针中设计并开发了一种高效的镍基异相催化剂。对 Ni/PiNe 催化剂进行了全面表征,并在微波辐照下进行了铃木-宫浦偶联测试。虽然镍是替代钯基催化体系的理想候选催化剂,但通常需要较高的催化剂用量,并需要利用配体和添加剂来提高反应速率。相反,使用我们的新型 Ni/PiNe 催化剂,只需极低的催化剂用量,在不使用配体的情况下,就能高效合成 30 种不同的产品,分离产率高达 93%。此外,Ni/PiNe 催化剂还显示出良好的连续循环耐久性和令人印象深刻的吨值 (1140)。除了在短反应时间内的催化效率以及在兆瓦级辐照下的稳定性和耐久性之外,Ni/PiNe 催化剂还可以进一步优化,实现较低的 E 因子值(14.0),从而凸显了进一步减少废物和降低相关工艺成本的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ni/PiNe Heterogeneous Catalyst from Biomass Waste: Low-Loading, Ligand-Free Suzuki-Miyaura Cross-Coupling.

An efficient Ni-based heterogeneous catalyst from pine needles urban waste valorization was designed and developed with a resource recycling strategy. The Ni/PiNe catalyst was fully characterized and tested in the Suzuki-Miyaura coupling under microwave irradiation. Although Ni is a promising candidate for replacing Pd-based catalytic systems, it generally requires a high catalyst amount and the exploitation of ligands and additives to enhance the reaction rate. On the contrary, with our new Ni/PiNe, 30 different products were efficiently synthesized with an isolated yield of up to 93 %, using a very low catalyst amount and in the absence of ligands. Furthermore, the Ni/PiNe catalyst also showed good durability for consecutive cycles and an impressive TON value (1140). In addition to the catalytic efficiency in short reaction time and to the stability and durability under MW irradiation, the Ni/PiNe allowed for further optimization, achieving a low E-factor value (14.0), thus highlighting the potential in further reducing the waste and costs associated to the process.

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来源期刊
ChemSusChem
ChemSusChem 化学-化学综合
CiteScore
15.80
自引率
4.80%
发文量
555
审稿时长
1.8 months
期刊介绍: ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology
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