Ce3+ 离子对 Ba-Sn 硼磷酸盐玻璃的光学和辐射屏蔽性能的影响

IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL
A. Paul Dhinakaran, P. Vinothkumar, S. Praveenkumar, Manoj Mohapatra
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引用次数: 0

摘要

本研究旨在探究掺杂 Ce3+ 的硼磷化钡锡玻璃的结构、光学和机械特性,以确定其在核辐射屏蔽中的潜在应用。掺杂 Ce3+ 的硼磷化钡锡玻璃(50B2O3+20 P2O5+10TiO2+6SrCO3+4SnO+4BaF2+5BaCO3+1Ce2O3 )是根据早期研究采用熔体淬火法生产的。粉末 X 射线衍射研究验证了 Ce3+ 掺杂硼酸钡锡玻璃的无定形性质。使用傅立叶变换-RAMAN 和傅立叶变换红外光谱测定了掺杂 Ce3+ 的硼酸钡锡玻璃的官能团。利用紫外-可见光谱对掺杂 Ce3+ 的硼磷化钡锡玻璃进行了检测。这些特性包括光带隙、消光系数、光导率和折射率。通过 EDAX 和 SEM 分析,研究了掺杂 Ce3+ 的硼酸钡锡玻璃的化学成分和表面形态。使用光致发光技术研究了掺杂 Ce3+ 的硼酸钡锡玻璃的激发光谱和发射光谱。同时还研究了玻璃的 CIE 坐标。此外,还使用 Phy-X 软件研究了玻璃的质量衰减系数、半值层、平均自由路径、十值层和 EABF 等伽马射线屏蔽特性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The effect of Ce3+ ions on the optical, and radiation shielding properties in Ba–Sn borophosphate glass
This study aims to investigate the structural, optical, and mechanical properties of Ce3+ doped Barium Tin Borophosphate glass for potential applications in nuclear radiation shielding. The Ce3+ Doped Barium Tin Borophosphate glass (50B2O3+20 P2O5+10TiO2+6SrCO3+4SnO+ 4BaF2+5BaCO3+1Ce2O3) was produced according to earlier research, melt quenching method. The amorphous nature of Ce3+ Doped Barium Tin Borophosphate glass was verified by powder X-ray diffraction investigation. The Ce3+ Doped Barium Tin Borophosphate glass's functional groups were determined using Fourier transform-RAMAN and Fourier transform infrared spectroscopy. Using Ultraviolet-Visible spectroscopy the Ce3+ Doped Barium Tin Borophosphate glass was examined. These properties included its optical band gap, extinction coefficient, optical conductivity, and refractive index. Using EDAX and SEM analyses, the chemical compositions and surface morphology of the Ce3+ Doped Barium Tin Borophosphate glass were examined. Ce3+ doped barium tin Borophosphate glass was studied in terms of its excitation and emission spectra using the photoluminescence technique. The glass's CIE coordinates were also looked at. Additionally, the mass attenuation coefficient, half-value layer, mean free path, tenth value layer, and EABF were studied concerning the glass's gamma-ray shielding qualities using the Phy-X software.
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来源期刊
Radiation Physics and Chemistry
Radiation Physics and Chemistry 化学-核科学技术
CiteScore
5.60
自引率
17.20%
发文量
574
审稿时长
12 weeks
期刊介绍: Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.
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