构建具有增强可见光驱动光催化活性的磁性 Ag3PO4/Fe3O4/Chitosan 聚合物,用于降解亚甲基蓝染料

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL
Annette Jayam Somasundaram, Elaiyappillai Elanthamilan, Sea-Fue Wang, I. Sharmila Lydia
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引用次数: 0

摘要

本研究采用简单的共沉淀方法,然后用超声波处理生成了一种由磁性 Ag3PO4/Fe3O4/Chitosan(CS) 组成的复合材料。利用傅立叶变换红外(FTIR)、扫描电子显微镜(SEM)、X 射线衍射(XRD)、振动样品磁力计(VSM)和 X 射线光电子能谱(XPS)方法对磁性 Ag3PO4/Fe3O4/CS 复合材料进行了表征。该磁性复合材料被评估为一种光催化剂,可在可见光照射下降解亚甲基蓝(MB)。研究还侧重于优化光催化剂的剂量、浓度波动和稳定性,以改善染料降解的反应条件。磁性 Ag3PO4/Fe3O4/CS 复合材料在降解甲基溴方面表现出很强的光催化活性,去除效率高达 95%。此外,对磁性复合材料的可回收性进行了连续五个周期的评估,降解效率仅降低到 85%,这证明了它的稳健性。该复合材料表现出卓越的可回收性和可再利用性,同时催化活性没有下降。这项研究的结果将有助于生产易于分离的磁性 Ag3PO4/Fe3O4/CS 复合材料作为异相催化剂,从而推动环境友好型纳米技术的发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation

The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag3PO4/Fe3O4/Chitosan(CS). The magnetic Ag3PO4/Fe3O4/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag3PO4/Fe3O4/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag3PO4/Fe3O4/CS composite as heterogeneous catalysts.

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来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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