Yingzi Lin , Mengshi Wang , Junjie Chen , Siwen Li , Yuanyuan Zhang , Liangliang Wei , Ningning Sun , Chengyu Liu , Junjie Zhao
{"title":"紫外线增强 Fe2+/PDS 系统降解酸性橙 7:动力学、降解机制和毒性评估","authors":"Yingzi Lin , Mengshi Wang , Junjie Chen , Siwen Li , Yuanyuan Zhang , Liangliang Wei , Ningning Sun , Chengyu Liu , Junjie Zhao","doi":"10.1016/j.jphotochem.2024.116054","DOIUrl":null,"url":null,"abstract":"<div><div>Based on the deficiency of the Fe<sup>2+</sup> catalyzed persulfate (PDS) process, ultraviolet (UV) synergistic Fe<sup>2+</sup> activated PDS system was introduced in this study for the degradation of acid orange 7 (AO7) dye. The effects of different initial pH, PDS dosage, Fe<sup>2+</sup> dosage, and different UV intensities on the degradation rate of AO7 were investigated, and a kinetic model for the apparent reaction rate was determined. The results showed that the UV/Fe<sup>2+</sup>/PDS system was effective in degrading AO7 in a wide pH range. Under optimal conditions, 96 % removal of AO7 was achieved in 10 min. The effects of different inorganic anions on AO7 were discussed; Cl<sup>−</sup> had little effect on the degradation effect, and SO<sub>4</sub><sup>2−</sup>, NO<sub>3</sub><sup>−</sup> and HCO<sub>3</sub><sup>−</sup> inhibited the degradation of AO7 by the system to varying degrees. The presence of reactive radicals (SO<sub>4</sub><sup>·−</sup> and·OH) in the reaction was determined by quenching experiments and EPR capture and their degradation contribution was further investigated. Nine intermediates of AO7 were detected by LC-MS/MS, and the degradation pathway of AO7 was inferred by combining with UV-Vis spectra. Finally, the ecotoxicity and tritogenic effects of AO7 intermediates were assessed by Toxtree and T.E.S.T toxicity prediction models, which showed that the final degradation product toxicity was non-mutagenic, non-teratogenic, and devoid of hereditary and non-hereditary carcinogenicity.</div></div>","PeriodicalId":16782,"journal":{"name":"Journal of Photochemistry and Photobiology A-chemistry","volume":"460 ","pages":"Article 116054"},"PeriodicalIF":4.1000,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"UV-enhanced Fe2+/PDS system for degradation of acid orange 7: Kinetics, degradation mechanism and toxicity assessment\",\"authors\":\"Yingzi Lin , Mengshi Wang , Junjie Chen , Siwen Li , Yuanyuan Zhang , Liangliang Wei , Ningning Sun , Chengyu Liu , Junjie Zhao\",\"doi\":\"10.1016/j.jphotochem.2024.116054\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Based on the deficiency of the Fe<sup>2+</sup> catalyzed persulfate (PDS) process, ultraviolet (UV) synergistic Fe<sup>2+</sup> activated PDS system was introduced in this study for the degradation of acid orange 7 (AO7) dye. The effects of different initial pH, PDS dosage, Fe<sup>2+</sup> dosage, and different UV intensities on the degradation rate of AO7 were investigated, and a kinetic model for the apparent reaction rate was determined. The results showed that the UV/Fe<sup>2+</sup>/PDS system was effective in degrading AO7 in a wide pH range. Under optimal conditions, 96 % removal of AO7 was achieved in 10 min. The effects of different inorganic anions on AO7 were discussed; Cl<sup>−</sup> had little effect on the degradation effect, and SO<sub>4</sub><sup>2−</sup>, NO<sub>3</sub><sup>−</sup> and HCO<sub>3</sub><sup>−</sup> inhibited the degradation of AO7 by the system to varying degrees. The presence of reactive radicals (SO<sub>4</sub><sup>·−</sup> and·OH) in the reaction was determined by quenching experiments and EPR capture and their degradation contribution was further investigated. Nine intermediates of AO7 were detected by LC-MS/MS, and the degradation pathway of AO7 was inferred by combining with UV-Vis spectra. Finally, the ecotoxicity and tritogenic effects of AO7 intermediates were assessed by Toxtree and T.E.S.T toxicity prediction models, which showed that the final degradation product toxicity was non-mutagenic, non-teratogenic, and devoid of hereditary and non-hereditary carcinogenicity.</div></div>\",\"PeriodicalId\":16782,\"journal\":{\"name\":\"Journal of Photochemistry and Photobiology A-chemistry\",\"volume\":\"460 \",\"pages\":\"Article 116054\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-10-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Photochemistry and Photobiology A-chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1010603024005987\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry and Photobiology A-chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1010603024005987","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
UV-enhanced Fe2+/PDS system for degradation of acid orange 7: Kinetics, degradation mechanism and toxicity assessment
Based on the deficiency of the Fe2+ catalyzed persulfate (PDS) process, ultraviolet (UV) synergistic Fe2+ activated PDS system was introduced in this study for the degradation of acid orange 7 (AO7) dye. The effects of different initial pH, PDS dosage, Fe2+ dosage, and different UV intensities on the degradation rate of AO7 were investigated, and a kinetic model for the apparent reaction rate was determined. The results showed that the UV/Fe2+/PDS system was effective in degrading AO7 in a wide pH range. Under optimal conditions, 96 % removal of AO7 was achieved in 10 min. The effects of different inorganic anions on AO7 were discussed; Cl− had little effect on the degradation effect, and SO42−, NO3− and HCO3− inhibited the degradation of AO7 by the system to varying degrees. The presence of reactive radicals (SO4·− and·OH) in the reaction was determined by quenching experiments and EPR capture and their degradation contribution was further investigated. Nine intermediates of AO7 were detected by LC-MS/MS, and the degradation pathway of AO7 was inferred by combining with UV-Vis spectra. Finally, the ecotoxicity and tritogenic effects of AO7 intermediates were assessed by Toxtree and T.E.S.T toxicity prediction models, which showed that the final degradation product toxicity was non-mutagenic, non-teratogenic, and devoid of hereditary and non-hereditary carcinogenicity.
期刊介绍:
JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds.
All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor).
The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.