硼硅玻璃在 900 ℃ 下对 H13 钢和 TZM 合金的润湿性和润滑性

IF 6.1 1区工程技术 Q1 ENGINEERING, MECHANICAL

Tribology International Pub Date : 2024-10-30 DOI:10.1016/j.triboint.2024.110360

Xuhui He , Yufei Wang , Minghui Lang , Xianzong Wang , Jianxi Liu , Long Wang , Jun Yang

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引用次数: 0

摘要

润滑可以减少机械运动部件的摩擦、磨损和氧化，从而达到保持设备工作稳定、高效和长寿命的目的。熔融润滑剂具有优异的抗摩擦、抗磨损和抗氧化性能，可用于钢的热金属成型工艺。TZM 合金是一种很有前途的锻造模具，可在热金属成型工艺中替代 H13 钢。本研究对硼硅玻璃在 H13 钢和 TZM 合金上的高温润湿性和高温摩擦学性能进行了研究。结果表明，玻璃在热 H13 钢上具有良好的润湿性和润滑性，900 ℃ 时的摩擦系数为 0.06。然而，同样的玻璃对 TZM 合金的润湿性和润滑性较差。这表明高温润湿性也是影响摩擦学性能的关键参数之一，而不是众所周知的高温粘度。表面和界面表征表明，Fe2O3 诱导基体表面附近的网络改性剂 Na+ 富集，致密且可剪切的低氧渗透玻璃膜使 H13 钢（销钉）在摩擦体系中具有优异的抗氧化性和润滑性能。MoO3 对硼硅酸盐熔体的侵蚀导致粘附性变差，玻璃聚合区和钼酸盐解聚区出现相分离行为。低熔点物种的熔化状态使 TZM 合金（销钉）摩擦系统表现出复杂的摩擦行为。这项工作将为结构和润湿性控制提供一些指导，从而有望实现高温润滑。

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Wettability and lubricity of borosilicate glass to H13 steel and TZM alloy at 900 ℃

Lubrication can reduce friction, wear and oxidation of mechanical moving parts to achieve the purpose of maintaining the working stability, high efficiency and long life of the device. Melt lubricants have excellent anti-friction, anti-wear and anti-oxidation properties and are used in the hot metal forming process for steels. TZM alloy is a promising forging die to replace H13 steel in the hot metal forming process. In this study, the high temperature wettability and high temperature tribological performance of borosilicate glass on H13 steel and TZM alloy were studied. The results suggest that the glass has good wettability on the hot H13 steel and promising lubricating with coefficient of friction of 0.06 at 900 ℃. However, the same glass shows poor wettability and lubricating for the TZM alloy. It indicates that high temperature wettability is also one of the key parameters that influence the tribological performance, rather than the well-known high temperature viscosity. Surface and interface characterization indicates that the Fe₂O₃ induced enrichment of the network modifier Na⁺ near the substrate surface, the dense and shearable low-oxygen permeable glass film led to the excellent oxidation resistance and lubrication properties in the friction system of H13 steel (pin). The erosion of the borosilicate melt by MoO₃ leads to poor adhesion, the phase separation behavior of the glass polymerization zone and the molybdate depolymerization zone. The melting state of the low melting point species make the TZM alloy (pin) friction system exhibit complex friction behavior. This work will provide some guideline for the structure and wettability control for promising high temperature lubricating.

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来源期刊

Tribology International 工程技术-工程：机械

CiteScore

10.10

自引率

16.10%

发文量

627

审稿时长

35 days

期刊介绍： Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.