{"title":"基于 3-(1-苯基-2,3-二甲基吡唑酮-5)偶氮戊二酮-2,4 的新型化合物的合成、X 射线分析、比电导率研究和抗氧化活性","authors":"Esmira Eyyubova , Famil Chiragov , Faik Musayev , Khalil Nagiyev , Namiq Shikhaliyev , Vagif Farzaliyev , Afsun Sujayev","doi":"10.1016/j.jics.2024.101473","DOIUrl":null,"url":null,"abstract":"<div><div>A reagent 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 was synthesized and isolated into crystalline form based on 4-amino-antipyrine and acetylacetone. Subsequently, 2 molecules of 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 were cross-linked with ethylenediamine and a novel reagent 4-((E)-(2-((2-((1R)-2-(1,5-dimethyl-3-oxo-2-phenylpyrazolidin-4-yl)-4,4,5-trimethyl-4,5-dihydro-1H-1<sup>λ</sup>4,2<sup>λ</sup>4,3-triazol-1-yl)ethyl)amino)-4-oxopentan-3-yl)diazenyl)-1,5-dimethyl-2 phenylpyrazolidin-3-one.</div><div>Single crystals of the resulting product were obtained and its main characteristics were studied. Using X-ray diffraction analysis, the structure of the synthesized product was studied and the parameters of the crystal cell were determined. The stability constants and specific electric conductivity of resulting complexes of R<sub>2</sub> with Fe<sup>3+</sup>, Cu<sup>2+</sup>, Cd<sup>2+</sup>, Zn<sup>2+</sup>, Co<sup>2+</sup>, Mn<sup>2+</sup>, Ni<sup>2+</sup> ions were calculated.</div><div>The antioxidant properties of the synthesized compounds were investigated in model reactions using the kinetic method. It was found that the synthesized compounds are effective inhibitors of hydrocarbon oxidation.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"101 12","pages":"Article 101473"},"PeriodicalIF":3.2000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, X-ray analysis, specific electric conductivity study and antioxidant activity of novel compound based on 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4\",\"authors\":\"Esmira Eyyubova , Famil Chiragov , Faik Musayev , Khalil Nagiyev , Namiq Shikhaliyev , Vagif Farzaliyev , Afsun Sujayev\",\"doi\":\"10.1016/j.jics.2024.101473\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A reagent 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 was synthesized and isolated into crystalline form based on 4-amino-antipyrine and acetylacetone. Subsequently, 2 molecules of 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 were cross-linked with ethylenediamine and a novel reagent 4-((E)-(2-((2-((1R)-2-(1,5-dimethyl-3-oxo-2-phenylpyrazolidin-4-yl)-4,4,5-trimethyl-4,5-dihydro-1H-1<sup>λ</sup>4,2<sup>λ</sup>4,3-triazol-1-yl)ethyl)amino)-4-oxopentan-3-yl)diazenyl)-1,5-dimethyl-2 phenylpyrazolidin-3-one.</div><div>Single crystals of the resulting product were obtained and its main characteristics were studied. Using X-ray diffraction analysis, the structure of the synthesized product was studied and the parameters of the crystal cell were determined. The stability constants and specific electric conductivity of resulting complexes of R<sub>2</sub> with Fe<sup>3+</sup>, Cu<sup>2+</sup>, Cd<sup>2+</sup>, Zn<sup>2+</sup>, Co<sup>2+</sup>, Mn<sup>2+</sup>, Ni<sup>2+</sup> ions were calculated.</div><div>The antioxidant properties of the synthesized compounds were investigated in model reactions using the kinetic method. It was found that the synthesized compounds are effective inhibitors of hydrocarbon oxidation.</div></div>\",\"PeriodicalId\":17276,\"journal\":{\"name\":\"Journal of the Indian Chemical Society\",\"volume\":\"101 12\",\"pages\":\"Article 101473\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Indian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0019452224003534\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Indian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0019452224003534","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, X-ray analysis, specific electric conductivity study and antioxidant activity of novel compound based on 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4
A reagent 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 was synthesized and isolated into crystalline form based on 4-amino-antipyrine and acetylacetone. Subsequently, 2 molecules of 3-(1-phenyl-2,3-dimethylpyrazolone-5)azopentadione-2,4 were cross-linked with ethylenediamine and a novel reagent 4-((E)-(2-((2-((1R)-2-(1,5-dimethyl-3-oxo-2-phenylpyrazolidin-4-yl)-4,4,5-trimethyl-4,5-dihydro-1H-1λ4,2λ4,3-triazol-1-yl)ethyl)amino)-4-oxopentan-3-yl)diazenyl)-1,5-dimethyl-2 phenylpyrazolidin-3-one.
Single crystals of the resulting product were obtained and its main characteristics were studied. Using X-ray diffraction analysis, the structure of the synthesized product was studied and the parameters of the crystal cell were determined. The stability constants and specific electric conductivity of resulting complexes of R2 with Fe3+, Cu2+, Cd2+, Zn2+, Co2+, Mn2+, Ni2+ ions were calculated.
The antioxidant properties of the synthesized compounds were investigated in model reactions using the kinetic method. It was found that the synthesized compounds are effective inhibitors of hydrocarbon oxidation.
期刊介绍:
The Journal of the Indian Chemical Society publishes original, fundamental, theorical, experimental research work of highest quality in all areas of chemistry, biochemistry, medicinal chemistry, electrochemistry, agrochemistry, chemical engineering and technology, food chemistry, environmental chemistry, etc.