热沙漠风化对普通软玉中高亲硒元素的影响

IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Kiran Shahood Almas, Richard D. Ash, Richard J. Walker
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引用次数: 0

摘要

已从热沙漠中回收了 20,000 多块陨石。有关热沙漠风化对高嗜酸性元素(HSE)的影响的研究很少。我们研究了三块不同风化等级的 L6 型普通软陨石的中性至弱酸性沥滤对 HSE 浓度和 Re-Os 同位素系统学的影响。我们描述了这些陨石大块样品 HSE 模式的特征,并进行了浸出时间逐渐延长的浸出实验,以确定在沙漠中长期居住可能产生的影响。与其他样本相比,风化程度最高的样本(NWA 14239)显示出更大的 HSE 浓度均一性,并且在浸出过程中释放出的 HSE 数量较少。水浸出比醋酸浸出更温和,与 NWA 869 的块状样本相比,并没有明显改变残留物的 Re-Os 同位素系统学。风化程度较低的样品(Viñales 和 NWA 869)的短期浸出物具有 187Os/188Os 比值较低的特点,表明早期太阳系形成的相位(如非磁性的软玉和具有低 Re/Os 的基质)优先溶解,而这些相位在风化程度最高的样品中已不再完整。在 HSE 中,钯对水和醋酸浸出的抵抗力最强,钯的最大去除率约为 5%,而 Re、Os 和 Ir 的移动性最强,去除率高达 40%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effects of hot desert weathering on highly siderophile elements in ordinary chondrites

Effects of hot desert weathering on highly siderophile elements in ordinary chondrites

Over 20,000 meteorites have been recovered from hot deserts. The effects of hot desert weathering upon highly siderophile elements (HSE) have been little studied. We have investigated the effects of neutral to mildly acidic leaching of three L6-type ordinary chondrites of different weathering grades on HSE concentrations and Re-Os isotopic systematics. We have characterized the bulk sample HSE patterns of these meteorites and conducted leaching experiments with progressively longer leaching times to determine the possible effects of long-term residence in a desert. The most weathered sample (NWA 14239) displayed greater HSE concentration homogeneity than the other samples and released lower quantities of HSEs during leaching. Water leaching was milder than acetic acid and did not significantly modify the Re-Os isotopic systematics of the residue relative to the bulk sample of NWA 869. Short-term leachates of the less weathered samples (Viñales and NWA 869) were characterized by low 187Os/188Os ratios, indicating the preferential dissolution of early solar system–formed phases such as non-magnetic chondrules and matrix with low Re/Os that are no longer intact in the most weathered sample. Of the HSE, Pd is most resistant to both water and acetic acid leaching, with a maximum removal of ~5% Pd, while Re, Os, and Ir are most mobile with up to 40% removal.

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来源期刊
Meteoritics & Planetary Science
Meteoritics & Planetary Science 地学天文-地球化学与地球物理
CiteScore
3.90
自引率
31.80%
发文量
121
审稿时长
3 months
期刊介绍: First issued in 1953, the journal publishes research articles describing the latest results of new studies, invited reviews of major topics in planetary science, editorials on issues of current interest in the field, and book reviews. The publications are original, not considered for publication elsewhere, and undergo peer-review. The topics include the origin and history of the solar system, planets and natural satellites, interplanetary dust and interstellar medium, lunar samples, meteors, and meteorites, asteroids, comets, craters, and tektites. Our authors and editors are professional scientists representing numerous disciplines, including astronomy, astrophysics, physics, geophysics, chemistry, isotope geochemistry, mineralogy, earth science, geology, and biology. MAPS has subscribers in over 40 countries. Fifty percent of MAPS'' readers are based outside the USA. The journal is available in hard copy and online.
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