封面专题:作为可充电锌-空气电池双功能电催化剂的金属有机框架材料(电池与超级电容器 11/2024)

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY
Fangqing Liu, Xiaoyi Lu, Chenglong Shi, Zhipeng Sun
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引用次数: 0

摘要

封面特写展示了在液态锌-空气电池系统中发生的催化氧还原(ORR)和氧进化(OER),以及电子的转移和 O2 与 OH- 之间的转换。图中展示了用于可充电锌-空气电池的 MOF 催化剂基本类型的形态。多孔结构和可调化学成分似乎是它们用作电催化剂的主要优势。由 MOF 衍生的碳基材料可作为牺牲模板,具有高活性、导电性和稳定性。在他们的综述(DOI: 10.1002/batt.202400402)中,Z. Sun 及其合作者介绍了三种金属有机骨架双功能催化剂(原始 MOF、MOF 衍生物和复合衍生物),并展示了它们如何为替代贵金属催化剂提供新的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cover Feature: Metal-Organic Framework Materials as Bifunctional Electrocatalyst for Rechargeable Zn-Air Batteries (Batteries & Supercaps 11/2024)

Cover Feature: Metal-Organic Framework Materials as Bifunctional Electrocatalyst for Rechargeable Zn-Air Batteries (Batteries & Supercaps 11/2024)

The Cover Feature shows catalytic oxygen reduction (ORR) and oxygen evolution (OER) taking place in a liquid zinc–air battery system with the transfer of electrons and conversion between O2 and OH. The morphologies of the basic types of MOF catalysts for rechargeable zinc–air batteries are illustrated. Their porous structure and tunable chemical composition seem to be the main advantages for their use as electrocatalysts. Carbon-based materials derived from the MOF act as sacrificial templates with high activity, electrical conductivity and stability. In their Review (DOI: 10.1002/batt.202400402), Z. Sun and co-workers present three kinds of metal–organic skeleton bifunctional catalysts (pristine MOFs, MOF derivatives and composite derivatives) and show how they offer new possibilities for replacing noble metal catalysts.

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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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