{"title":"基于 CoWO4/多壁碳纳米管的灵敏电化学传感器用于选择性测定盐酸氯丙嗪","authors":"Si Zeng, Peiyao Zhu, Deyu Liu, Yongmei Hu, Qitong Huang, Haiping Huang","doi":"10.1039/d4an01298d","DOIUrl":null,"url":null,"abstract":"In this work, a novel electrochemical sensor based on cobalt tungstate/multi-walled carbon nanotubes (CoWO4/MWCNTs) nanocomposite has been used to detect chlorpromazine hydrochloride (CPZ). The CoWO4/MWCNTs nanocomposite was obtained by solvothermal technology and ultrasonic method and analyzed via different characterization techniques of scanning electron microscope (SEM), X-ray diffractometer (XRD), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The electrochemical behavior of CoWO4/MWCNTs/GCE was explored using cyclic voltammetry (CV). Electrochemical experiments have confirmed that CoWO4/MWCNTs/GCE exhibits excellent electrocatalytic activity towards CPZ with good selectivity, reproducibility and stability. The linear dynamic range of CPZ was observed to be 1-2000 µM with a detection limit of 0.33 µM. Moreover, the actual sample was analyzed using lake water with satisfactory results, which endows the sensor as potential candidates for the detection of CPZ.","PeriodicalId":63,"journal":{"name":"Analyst","volume":"162 1","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A sensitive electrochemical sensor based on CoWO4/multi-walled carbon nanotubes for the selective determination of chlorpromazine hydrochloride\",\"authors\":\"Si Zeng, Peiyao Zhu, Deyu Liu, Yongmei Hu, Qitong Huang, Haiping Huang\",\"doi\":\"10.1039/d4an01298d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, a novel electrochemical sensor based on cobalt tungstate/multi-walled carbon nanotubes (CoWO4/MWCNTs) nanocomposite has been used to detect chlorpromazine hydrochloride (CPZ). The CoWO4/MWCNTs nanocomposite was obtained by solvothermal technology and ultrasonic method and analyzed via different characterization techniques of scanning electron microscope (SEM), X-ray diffractometer (XRD), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The electrochemical behavior of CoWO4/MWCNTs/GCE was explored using cyclic voltammetry (CV). Electrochemical experiments have confirmed that CoWO4/MWCNTs/GCE exhibits excellent electrocatalytic activity towards CPZ with good selectivity, reproducibility and stability. The linear dynamic range of CPZ was observed to be 1-2000 µM with a detection limit of 0.33 µM. Moreover, the actual sample was analyzed using lake water with satisfactory results, which endows the sensor as potential candidates for the detection of CPZ.\",\"PeriodicalId\":63,\"journal\":{\"name\":\"Analyst\",\"volume\":\"162 1\",\"pages\":\"\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analyst\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4an01298d\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analyst","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4an01298d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
A sensitive electrochemical sensor based on CoWO4/multi-walled carbon nanotubes for the selective determination of chlorpromazine hydrochloride
In this work, a novel electrochemical sensor based on cobalt tungstate/multi-walled carbon nanotubes (CoWO4/MWCNTs) nanocomposite has been used to detect chlorpromazine hydrochloride (CPZ). The CoWO4/MWCNTs nanocomposite was obtained by solvothermal technology and ultrasonic method and analyzed via different characterization techniques of scanning electron microscope (SEM), X-ray diffractometer (XRD), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The electrochemical behavior of CoWO4/MWCNTs/GCE was explored using cyclic voltammetry (CV). Electrochemical experiments have confirmed that CoWO4/MWCNTs/GCE exhibits excellent electrocatalytic activity towards CPZ with good selectivity, reproducibility and stability. The linear dynamic range of CPZ was observed to be 1-2000 µM with a detection limit of 0.33 µM. Moreover, the actual sample was analyzed using lake water with satisfactory results, which endows the sensor as potential candidates for the detection of CPZ.