A. I. Kovalev, D. L. Wainstein, E. P. Konovalov, V. O. Vakhrushev, S. A. Dmitrievskii, A. A. Tomchuk
{"title":"带 (TiAlCrSiY)N/(TiAlCr)N 涂层的切削工具表面摩擦陶瓷在高速干切削过程中的隔热性能和抗摩擦性能","authors":"A. I. Kovalev, D. L. Wainstein, E. P. Konovalov, V. O. Vakhrushev, S. A. Dmitrievskii, A. A. Tomchuk","doi":"10.1007/s11015-024-01809-z","DOIUrl":null,"url":null,"abstract":"<div><p>The physical mechanism of self-organization of a multilayer nanolaminated coating based upon non-equilibrium (TiAlCrSiY)N/(TiAlCr)N nitride on a cutting tool during high-speed (600 m/min.) dry cutting of N13 steel is established. Using a set of modern surface analysis methods coating degradation and tribo-oxidation are studied within the running-in and steady stages of wear. It is shown that during cutting, amorphous-nanocrystalline films of oxides similar to Cr<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub> (sapphire) and Al<sub>2</sub>O<sub>3</sub> · 2 (SiO<sub>2</sub>) (mullite) are formed within a wear crater. Using computer calculations by a finite element method, heat transfer is considered in the cutting zone during formation of protective tribo-oxides. It is found that among all tribo-oxides, mullite has the best thermal barrier properties. Oxidation is the main adaptation mechanism of a cutting tool under extreme mechanical and thermal shock during high-speed cutting. The topography of chip contact surface is studied at various cutting stages, which makes it possible to establish a change in plastic deformation mechanisms of treated metal and friction cutting modes. Quantum chemical calculations of the electron structure of mullite show the highest degree of its electron polarization and explain the radical drop in friction coefficient during film formation upon a wear surface. In this case, mullite acts as a solid lubricant.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 7","pages":"1001 - 1010"},"PeriodicalIF":0.8000,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermobarrier and antifriction properties of triboceramics on the surface of a cutting tool with (TiAlCrSiY)N/(TiAlCr)N coating during high-speed dry cutting\",\"authors\":\"A. I. Kovalev, D. L. Wainstein, E. P. Konovalov, V. O. Vakhrushev, S. A. Dmitrievskii, A. A. Tomchuk\",\"doi\":\"10.1007/s11015-024-01809-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The physical mechanism of self-organization of a multilayer nanolaminated coating based upon non-equilibrium (TiAlCrSiY)N/(TiAlCr)N nitride on a cutting tool during high-speed (600 m/min.) dry cutting of N13 steel is established. Using a set of modern surface analysis methods coating degradation and tribo-oxidation are studied within the running-in and steady stages of wear. It is shown that during cutting, amorphous-nanocrystalline films of oxides similar to Cr<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub> (sapphire) and Al<sub>2</sub>O<sub>3</sub> · 2 (SiO<sub>2</sub>) (mullite) are formed within a wear crater. Using computer calculations by a finite element method, heat transfer is considered in the cutting zone during formation of protective tribo-oxides. It is found that among all tribo-oxides, mullite has the best thermal barrier properties. Oxidation is the main adaptation mechanism of a cutting tool under extreme mechanical and thermal shock during high-speed cutting. The topography of chip contact surface is studied at various cutting stages, which makes it possible to establish a change in plastic deformation mechanisms of treated metal and friction cutting modes. Quantum chemical calculations of the electron structure of mullite show the highest degree of its electron polarization and explain the radical drop in friction coefficient during film formation upon a wear surface. In this case, mullite acts as a solid lubricant.</p></div>\",\"PeriodicalId\":702,\"journal\":{\"name\":\"Metallurgist\",\"volume\":\"68 7\",\"pages\":\"1001 - 1010\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-11-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Metallurgist\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11015-024-01809-z\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metallurgist","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11015-024-01809-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Thermobarrier and antifriction properties of triboceramics on the surface of a cutting tool with (TiAlCrSiY)N/(TiAlCr)N coating during high-speed dry cutting
The physical mechanism of self-organization of a multilayer nanolaminated coating based upon non-equilibrium (TiAlCrSiY)N/(TiAlCr)N nitride on a cutting tool during high-speed (600 m/min.) dry cutting of N13 steel is established. Using a set of modern surface analysis methods coating degradation and tribo-oxidation are studied within the running-in and steady stages of wear. It is shown that during cutting, amorphous-nanocrystalline films of oxides similar to Cr2O3, TiO2, Al2O3 (sapphire) and Al2O3 · 2 (SiO2) (mullite) are formed within a wear crater. Using computer calculations by a finite element method, heat transfer is considered in the cutting zone during formation of protective tribo-oxides. It is found that among all tribo-oxides, mullite has the best thermal barrier properties. Oxidation is the main adaptation mechanism of a cutting tool under extreme mechanical and thermal shock during high-speed cutting. The topography of chip contact surface is studied at various cutting stages, which makes it possible to establish a change in plastic deformation mechanisms of treated metal and friction cutting modes. Quantum chemical calculations of the electron structure of mullite show the highest degree of its electron polarization and explain the radical drop in friction coefficient during film formation upon a wear surface. In this case, mullite acts as a solid lubricant.
期刊介绍:
Metallurgist is the leading Russian journal in metallurgy. Publication started in 1956.
Basic topics covered include:
State of the art and development of enterprises in ferrous and nonferrous metallurgy and mining;
Metallurgy of ferrous, nonferrous, rare, and precious metals; Metallurgical equipment;
Automation and control;
Protection of labor;
Protection of the environment;
Resources and energy saving;
Quality and certification;
History of metallurgy;
Inventions (patents).