Performance, progress, and mechanism of g-C3N4-based photocatalysts in the degradation of pesticides: A systematic review

In the modern world, humans are exposed to an enormous number of pesticides discharged into the environment. Exposure to pesticides causes many health disorders, such as cancer, mental retardation, and endocrine disruption. Therefore, it is a priority to eliminate pesticides from contaminated water before discharge into aquatic environments. Conventional treatment systems do not efficiently accomplish pesticide remediation. Applying graphitic carbon nitride (g-C₃N₄; GCN)-based materials as highly efficient and low-cost catalysts can be one of the best methods for adequately removing pesticides. This study aims to review the most relevant studies on the use of GCN-based photocatalytic processes for degrading well-known pesticides in aqueous solutions. Thus, in the current state-of-the-art review, an overview is focused not only on how to use GCN-based photocatalysts towards the degradation of pesticides, but also discusses the impact of important operational factors like solution pH, mixture temperature, catalyst dosage, pesticide concentration, photocatalyst morphology, light intensity, reaction time, oxidant concentration, and coexisting anions. In this context, four common pesticides were reviewed, namely 2,4-dichlorophenoxyacetic acid (2,4-D), malathion (MTN), diazinon (DZN), and atrazine (ATZ). Following the screening procedure, 55 full-text papers were chosen, of which the most were published in 2023 (n = 10), and the most publications focused on the elimination of ATZ (n = 33). Among the GCN modification methods, integrating GCN with other photocatalysts showed the best performance in enhancing photocatalytic activity towards the degradation of pesticides. All GCN-based photocatalysts showed a degradation efficiency of > 90% for pesticides under optimum operating conditions. This review provides a detailed summary of different GCN modification methods to select the most promising and cost-effective photocatalyst degradation of pesticides.