含有噻唑、异噻唑、噻二唑和异噻二唑的氮光开关。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-11-07 DOI:10.1039/d4ob01573h

Nusaiba Madappuram Cheruthu , P. K. Hashim , Saugata Sahu , Kiyonori Takahashi , Takayoshi Nakamura , Hideyuki Mitomo , Kuniharu Ijiro , Nobuyuki Tamaoki

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引用次数: 0

摘要

我们报告了一类新型偶氮光开关，其中包含各种五元杂芳基单元，如噻唑、异噻唑、噻二唑和异噻二唑。这些偶氮光开关是利用 DFT 计算对 24 种化合物进行初步筛选，以确定最大吸收波长（λmax）为长波长的化合物。随后，合成了 8 种选定的氮光电开关。与其他合成的化合物相比，含有噻唑和异噻唑分子的化合物显示出相对较长的 λmax。在可见光照射下，这些氮光电开关在 430 nm、450 nm、470 nm（反式到顺式）和 525 nm（顺式到反式）波长处表现出可逆的异构化。对苯基偶氮[1,3,4-噻二唑]顺式异构体的 X 射线晶体结构分析表明，该异构体具有独特的正交几何形状。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Azophotoswitches containing thiazole, isothiazole, thiadiazole, and isothiadiazole†

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Azophotoswitches containing thiazole, isothiazole, thiadiazole, and isothiadiazole†

We report a novel class of azophotoswitches incorporating various five-membered heteroaryl units such as thiazole, isothiazole, thiadiazole, and isothiadiazole. These azophotoswitches were developed through an initial screening of 24 compounds using DFT calculations to identify those with the wavelength of maximum absorption (λ_max) at a long wavelength. Subsequently, eight selected azophotoswitches were synthesized. Compounds containing both thiazole and isothiazole moieties showed relatively long λ_max compared to the other synthesized compounds. These azophotoswitches exhibited reversible isomerization under visible light irradiation at 430 nm, 450 nm, 470 nm (trans to cis) and 525 nm (cis to trans). Analysis of the X-ray crystal structures of the cis isomer of phenylazo[1,3,4-thiadiazole] exhibited a unique orthogonal geometry.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.