Double Carbon-Species Coated Porous Silicon Anode Induced by Interfacial Energy Reduction for Lithium-Ion Batteries.

The rapid development of electric vehicles necessitates high-energy density Li-ion batteries for extended range. Silicon is a promising alternative to graphite anodes due to its high capacity; however, its substantial volume expansion during cycling leads to continuous growth of the solid electrolyte interphase and significant capacity fading. This study addresses these issues by designing a porous Si structure combined with a double carbon-species coating layer, induced by low interfacial energy in a scalable process. Carbon and graphene are located on Si surfaces, forming a close interface that maintains electrical contact, suppresses lithium consumption, and enhances charge transfer properties. The composite anode with a double carbon-species coating on Si demonstrates rapid stabilization with increasing coulombic efficiency, achieving a specific capacity of 1,814 mAh g-1 at 0.2 C and a high-rate capability of 1,356 mAh g-1 at 10C. Additionally, in a full-cell configuration with LiFePO4, it recorded a specific capacity of 161 mAh g-1 at 0.2 C. These results show the potential of porous Si with a carbon-graphene coating for stable, high-capacity operation in Li-ion batteries, offering new insights into high-performance electrochemical systems. Moreover, the double carbon-species coating derived from a scalable surface chemistry-based process presents a realistic alternative for industrial applications.