三氟甲烷硫酸钠介导的光催化芳香醛和醇的有氧氧化酯化反应。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-11-11 DOI:10.1039/d4ob01476f

Yong Liu, Xianjin Zhu, Yue Zhang, Zhengyi Yi, Xiaobo Yang, Hua Fu

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引用次数: 0

摘要

本研究开发了一种三氟甲烷亚磺酸钠介导的光催化芳香醛和醇的有氧氧化酯化策略，其中由易于获得且价格低廉的三氟甲烷亚磺酸钠和氧气在原位形成的五配位硫化物可作为光催化剂，并以中等至良好的产率提供相应的芳香酯。本方法是一种经济、环保的方案。

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Sodium trifluoromethanesulfinate-mediated photocatalytic aerobic oxidative esterification of aromatic aldehydes and alcohols.

A sodium trifluoromethanesulfinate-mediated photocatalytic strategy for the aerobic oxidative esterification of aromatic aldehydes and alcohols has been developed, in which the in situ formed pentacoordinate sulfide derived from readily available and inexpensive sodium trifluoromethanesulfinate and oxygen acts as the photocatalyst, and the corresponding aromatic esters were provided in moderate to good yields. The present method is an economical and environmentally friendly protocol.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： The international home of synthetic, physical and biomolecular organic chemistry.