用有机硅试剂对不饱和碳氢化合物进行双官能化处理的最新进展。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-11-13 DOI:10.1039/d4ob01471e

Jiawei Mao, Ming Chen, Yao Zhong, Ren-Jie Song

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引用次数: 0

摘要

有机硅化合物因其特殊的生物活性而备受关注。用有机硅试剂直接对不饱和碳氢化合物进行双官能化，以高效构建具有合成价值的硅官能化化合物，具有步骤和原子经济性高的特点，可在一个步骤中形成碳-硅/碳-碳键或碳-硅/碳-异键。本综述以不同的不饱和碳氢化合物为基础，总结了这一主题的最新进展以及典型实例和机理。

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Recent developments in difunctionalization of unsaturated hydrocarbons with organosilicon reagents.

Organosilicon compounds have attracted considerable attention because of their special biological activities. Direct difunctionalization of unsaturated hydrocarbons with organosilicon reagents for the efficient construction of synthetically valuable silicon-functionalized compounds are featured with a high step and atom economy, which could form carbon-silicon/carbon-carbon bonds or carbon-silicon/carbon-hetero bonds in one step. This review summarizes the recent advances on this topic based on different unsaturated hydrocarbons along with typical examples and mechanisms.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： The international home of synthetic, physical and biomolecular organic chemistry.