Hydrothermal-mediated in-situ nitrogen doping to prepare biochar for enhancing oxygen reduction reactions in microbial fuel cells

Nitrogen-doped carbon materials are deemed promising cathode catalysts for microbial fuel cells (MFCs). The challenge lies in reducing costs and enhancing the proportion of electrocatalytically active nitrogenous functional groups. This study proposes a hydrothermal-mediated in-situ doping method to produce nitrogen-doped biochar from aquatic plants. The nitrogen atoms are anchored in the carbon structure during hydrothermal treatment. Subsequent pyrolysis converts the hydrochar into a catalyst with highly catalytically active aromatic ring structure (HC-N+PY). The as-prepared HC-N+PY electrocatalyst demonstrates superior oxygen reduction reaction activity with half-wave potentials of 0.82 V. The MFC with HC-N+PY exhibits excellent performance, with a peak power density of 1444 mW/m². Theoretical calculations demonstrate that the synergistic effect of graphitic nitrogen and C–O groups at defect sites enhances O₂ adsorption and protonation. This work highlights the potential of utilizing nitrogen-doped biochar derived from aquatic plants as an effective catalyst for enhancing the performance of microbial fuel cells.