Jiahao Du, Haozhen Li, Jinhua Zhang, Wenhao Wang, Zhen Li, Qingchan Li, Jinxiang Li
{"title":"通过硫化改善纳米级零价铁的厌氧腐蚀和去污关系的动力学见解","authors":"Jiahao Du, Haozhen Li, Jinhua Zhang, Wenhao Wang, Zhen Li, Qingchan Li, Jinxiang Li","doi":"10.1016/j.cej.2024.157638","DOIUrl":null,"url":null,"abstract":"There is a trade-off between corrosion and decontamination of nanoscale zero-valent iron (nZVI), which can be modulated by the sulfidation. Despite that, the insights into the relationship between anaerobic corrosion and decontamination of sulfidated nZVI (S-nZVI) remain unclear from a kinetic point of view. Herein, we used the variation of open-circuit potential to explore the anaerobic corrosion kinetic of S-nZVI. Taking Cr(VI) as the targeted contaminant, a negative correlation between decontamination and the corrosion of S-nZVI was identified during the first 10 min of reaction (R<sup>2</sup> = 0.6919, slope = -0.7091) and after the 10 min of reaction (R<sup>2</sup> = 0.7556, slope = -0.1307). Based on the results of TEM mapping, electrochemical impedance spectroscopy and XPS, this study further revealed that sulfidation not only enhanced the mass transfer of Cr(VI) toward nZVI in the initial stage of reaction, but also improved the electron transfer of nZVI toward Cr(VI) in the later stage of reaction. The ultimately enhanced removal and reduction of Cr(VI) by S-nZVI should be attributed to the introduction of iron sulfides (FeS<sub>x</sub>) that not only promoted the conductivity but also favored the affinity of nZVI toward Cr(VI). Overall, the kinetic insights presented in this study are valuable for understanding the process mechanisms of S-nZVI in anaerobic water and may extend to provide theoretical support for the development of enhanced methods for the remediation of contaminated groundwater using nZVI.","PeriodicalId":270,"journal":{"name":"Chemical Engineering Journal","volume":"20 1","pages":""},"PeriodicalIF":13.3000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Kinetic insights into the relationships between anaerobic corrosion and decontamination of nanoscale zerovalent iron improved by sulfidation\",\"authors\":\"Jiahao Du, Haozhen Li, Jinhua Zhang, Wenhao Wang, Zhen Li, Qingchan Li, Jinxiang Li\",\"doi\":\"10.1016/j.cej.2024.157638\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"There is a trade-off between corrosion and decontamination of nanoscale zero-valent iron (nZVI), which can be modulated by the sulfidation. Despite that, the insights into the relationship between anaerobic corrosion and decontamination of sulfidated nZVI (S-nZVI) remain unclear from a kinetic point of view. Herein, we used the variation of open-circuit potential to explore the anaerobic corrosion kinetic of S-nZVI. Taking Cr(VI) as the targeted contaminant, a negative correlation between decontamination and the corrosion of S-nZVI was identified during the first 10 min of reaction (R<sup>2</sup> = 0.6919, slope = -0.7091) and after the 10 min of reaction (R<sup>2</sup> = 0.7556, slope = -0.1307). Based on the results of TEM mapping, electrochemical impedance spectroscopy and XPS, this study further revealed that sulfidation not only enhanced the mass transfer of Cr(VI) toward nZVI in the initial stage of reaction, but also improved the electron transfer of nZVI toward Cr(VI) in the later stage of reaction. The ultimately enhanced removal and reduction of Cr(VI) by S-nZVI should be attributed to the introduction of iron sulfides (FeS<sub>x</sub>) that not only promoted the conductivity but also favored the affinity of nZVI toward Cr(VI). Overall, the kinetic insights presented in this study are valuable for understanding the process mechanisms of S-nZVI in anaerobic water and may extend to provide theoretical support for the development of enhanced methods for the remediation of contaminated groundwater using nZVI.\",\"PeriodicalId\":270,\"journal\":{\"name\":\"Chemical Engineering Journal\",\"volume\":\"20 1\",\"pages\":\"\"},\"PeriodicalIF\":13.3000,\"publicationDate\":\"2024-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering Journal\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1016/j.cej.2024.157638\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.cej.2024.157638","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Kinetic insights into the relationships between anaerobic corrosion and decontamination of nanoscale zerovalent iron improved by sulfidation
There is a trade-off between corrosion and decontamination of nanoscale zero-valent iron (nZVI), which can be modulated by the sulfidation. Despite that, the insights into the relationship between anaerobic corrosion and decontamination of sulfidated nZVI (S-nZVI) remain unclear from a kinetic point of view. Herein, we used the variation of open-circuit potential to explore the anaerobic corrosion kinetic of S-nZVI. Taking Cr(VI) as the targeted contaminant, a negative correlation between decontamination and the corrosion of S-nZVI was identified during the first 10 min of reaction (R2 = 0.6919, slope = -0.7091) and after the 10 min of reaction (R2 = 0.7556, slope = -0.1307). Based on the results of TEM mapping, electrochemical impedance spectroscopy and XPS, this study further revealed that sulfidation not only enhanced the mass transfer of Cr(VI) toward nZVI in the initial stage of reaction, but also improved the electron transfer of nZVI toward Cr(VI) in the later stage of reaction. The ultimately enhanced removal and reduction of Cr(VI) by S-nZVI should be attributed to the introduction of iron sulfides (FeSx) that not only promoted the conductivity but also favored the affinity of nZVI toward Cr(VI). Overall, the kinetic insights presented in this study are valuable for understanding the process mechanisms of S-nZVI in anaerobic water and may extend to provide theoretical support for the development of enhanced methods for the remediation of contaminated groundwater using nZVI.
期刊介绍:
The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.