非线性光学钼/钨碲化物的最新进展:结构、晶体生长和表征

IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Jingfang Zhou , Qian Wu , Aimin Ji , Zhen Jia , Mingjun Xia
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引用次数: 0

摘要

由于二阶非线性光学(NLO)材料在光电技术中的应用潜力,为中红外(中红外,3-5 μm)应用研究二阶非线性光学(NLO)材料一直是一个重要的研究前沿。在这篇综述中,我们重点研究了含有 d0 过渡金属阳离子(Mo6+/W6+)和具有立体化学活性孤电子对的 Te4+ 阳离子的非中心对称(NCS)钼/钨碲化物,它们容易发生二阶贾恩-泰勒(SOJT)畸变。这些化合物表现出卓越的 NLO 效应、3-5 μm 范围内的高透光率、适度的双折射以及易于在环境条件下生长晶体。此外,与传统的中红外 NLO 材料(如金属磷化物和掺杂镓化合物)相比,它们具有更宽的带隙,从而增强了抗激光损伤的能力。我们根据阳离子类型将著名的 NCS 钼/钨碲化物分为九个系列,主要集中在三元和四元体系。综述概述了它们的合成方法、晶体结构、生长技术和物理性质,重点介绍了 SOJT 活性单元、NCS 结构和 NLO 性能之间的关系。这项工作为人们了解这些材料提供了一个清晰的视角,旨在加速探索高性能中红外 NLO 晶体,以满足日益增长的技术需求。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizations
The pursuit of second-order nonlinear optical (NLO) materials for mid-infrared (mid-IR, 3–5 μm) applications has been a significant research frontier due to their potential in optoelectronic technologies. In this review, we focus on noncentrosymmetric (NCS) molybdenum/tungsten tellurites incorporating d0 transition metal cations (Mo6+/W6+) and Te4+ cation with stereo-chemically active lone electron pair, which are prone to the second-order Jahn-Teller (SOJT) distortions. These compounds exhibit exceptional NLO effects, high optical transmittance in the 3–5 μm range, moderate birefringence, and ease of crystal growth in ambient conditions. Furthermore, they possess wider band gaps compared to conventional mid-IR NLO materials like metal phosphides and chalcogenides, enhancing their laser damage resistances. We categorize the notable NCS molybdenum/tungsten tellurites into nine series based on their cationic types, concentrating on ternary and quaternary systems. The review outlines their synthesis methods, crystal structures, growth techniques, and physical properties, with an emphasis on the relationship between SOJT-active units, NCS structures, and NLO performances. This work provides a clear perspective on the understanding of these materials and aims to accelerate the exploration of high-performance mid-IR NLO crystals to meet the increasing technological demands.
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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