利用 α-SnWO4 与 g-C3N4 纳米复合材料高效光催化降解废水中的有机污染物。

S P Keerthana, R Yuvakkumar, G Ravi, V Ravi Sankar, S Arun Metha, Suresh Sagadevan
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引用次数: 0

摘要

在这个工业化时代,废水管理已成为满足世界用水需求的必要条件。废水是造成环境恶化的主要危机之一。光催化被认为是去除污染物的最佳方法。因此,本研究采用水热法制备了纯 g-C3N4-SnWO4 纳米复合材料。通过各种技术对制备的复合材料进行了研究。g-C3N4 的引入改变了 SnWO4 的带隙。在 SnWO4 中加入 g-C3N4 后,其形貌得到了均匀的发展。以伊万斯蓝染料作为模型污染物。加入 g-C3N4 与 SnWO4 形成异质结后,光催化作用得到改善。EB、SnWO4-EB、0.1g g-C3N4-SnWO4-EB 和 0.2g g-C3N4-SnWO4-EB 的计算速率常数分别为 0.000878、0.0068、0.01 和 0.0122 min-1。0.2 g-C3N4-SnWO4 光催化剂的速率常数有所增加。g-C3N4 和 SnWO4 之间出现的异质结促进了 SnWO4 更好地分离 e-/h+ 对,降低了重组率,从而增强了产物的光催化作用。0.2 克 g-C3N4-SnWO4 是未来废水降解的理想候选材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Efficient photocatalytic degradation of organic pollutants using α-SnWO4 with g-C3N4 nanocomposites for wastewater remediation.

Wastewater management has become necessary in this industrialized era to meet the water needs of the world. Wastewater is one of the major crises in depletion of the environment. Photocatalysis is considered as the best way to remove pollutants. Therefore, in this study, pure and g-C3N4-SnWO4 nanocomposites were produced employing hydrothermal route. Prepared composites were studied by various techniques. SnWO4 band gap were altered by introduction of g-C3N4. The morphology was uniformly developed by the addition of g-C3N4 to the SnWO4. Evans Blue dye was employed as model pollutant. The photocatalytic action was improved by adding g-C3N4, which formed a heterojunction with SnWO4. The calculated rate constant was 0.000878, 0.0068, 0.01 and 0.0122 min-1 for EB, SnWO4-EB, 0.1g g-C3N4-SnWO4-EB and 0.2g g-C3N4-SnWO4-EB. The rate constant increased for 0.2 g g-C3N4-SnWO4 photocatalyst. A heterojunction appeared between g-C3N4 and SnWO4 facilitated SnWO4 for better e-/h+pair's separation and a lower recombination rate, which increased photocatalytic action of product. 0.2 g of g-C3N4-SnWO4 is a promising candidate for future wastewater degradation.

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