铟催化硝基烯烃与芳香胺的氢硅烷化反应

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-11-11 DOI:10.1039/D4DT02861A

Gobbilla Sai Kumar, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar and Tarun K. Panda

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引用次数: 0

摘要

在此，我们报告了由不同螯合配体（L1-L3）支持的三种铟配合物（1-3）的合成过程。我们利用多核核磁共振对这些铟金属配合物进行了表征，并通过单晶 X 射线晶体学证实了它们的固态结构。铟配合物 1（5 摩尔%）在苯基硅烷和 NaI 的存在下有效地还原了硝基烯烃。在标准条件下，含有不同官能度的硝基arenes 被还原，并以良好的产率得到相应的胺。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Indium-catalyzed hydrosilylation of nitroarenes to aromatic amines†

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Indium-catalyzed hydrosilylation of nitroarenes to aromatic amines†

Herein, we report the synthesis of three indium complexes (1–3) supported by different chelating ligands (L1–L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures were confirmed by single-crystal X-ray crystallography. The indium complex 1 (5 mol%) effectively reduced nitroarenes in the presence of phenylsilane and NaI. Nitroarenes containing different functionalities were reduced under standard conditions to give the corresponding amines in good yields.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.