Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda
{"title":"铟催化硝基烯烃与芳香胺的氢硅烷化反应","authors":"Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda","doi":"10.1039/d4dt02861a","DOIUrl":null,"url":null,"abstract":"Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures were confirmed by single-crystal X-ray crystallography. The indium complex 1 (5 mol%) effectively reduced nitroarenes in the presence of phenylsilane and NaI. Nitroarenes containing different functionalities were reduced under standard conditions to give the corresponding amines in good yields.","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Indium-Catalyzed Hydrosilylation of Nitroarenes to Aromatic Amines\",\"authors\":\"Sai Kumar Gobbilla, Kulsum Bano, Priyabrata Biswal, Soumyadip Dey, Ravi Kumar, Abhijit Sau, Vadapalli Chandrasekhar, Tarun Kanti Panda\",\"doi\":\"10.1039/d4dt02861a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures were confirmed by single-crystal X-ray crystallography. The indium complex 1 (5 mol%) effectively reduced nitroarenes in the presence of phenylsilane and NaI. Nitroarenes containing different functionalities were reduced under standard conditions to give the corresponding amines in good yields.\",\"PeriodicalId\":3,\"journal\":{\"name\":\"ACS Applied Electronic Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Electronic Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4dt02861a\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt02861a","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
摘要
在此，我们报告了由不同螯合配体（L1-L3）支持的三种铟配合物（1-3）的合成过程。我们利用多核核磁共振对这些铟金属配合物进行了表征，并通过单晶 X 射线晶体学证实了它们的固态结构。铟配合物 1（5 摩尔%）在苯基硅烷和 NaI 的存在下有效地还原了硝基烯烃。在标准条件下，含有不同官能度的硝基arenes 被还原，并以良好的产率得到相应的胺。
Indium-Catalyzed Hydrosilylation of Nitroarenes to Aromatic Amines
Herein, we report the synthesis of three indium complexes (1-3) supported by different chelating ligands (L1-L3). The indium metal complexes were characterized by using multinuclear NMR, and their solid-state structures were confirmed by single-crystal X-ray crystallography. The indium complex 1 (5 mol%) effectively reduced nitroarenes in the presence of phenylsilane and NaI. Nitroarenes containing different functionalities were reduced under standard conditions to give the corresponding amines in good yields.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
