相转移催化剂结构对聚对苯二甲酸乙二醇酯碱性水解的影响

IF 9.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2024-10-11 DOI:10.1039/D4GC05070C

Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin and Stephen J. Connon

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引用次数: 0

摘要

通过对 50 种用于水解聚对苯二甲酸乙二酯的简单（大部分）季铵和卤化鏻催化剂中影响催化活性的因素进行系统研究，发现了最有效的构型异构体类别以及这些催化剂应具备的最佳特性。提供了催化剂设计的一般指导原则。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)†

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Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)†

A systematic investigation into the factors which influence catalytic activity in 50 simple (mostly) quaternary ammonium- and phosphonium halide catalysts for the hydrolysis of poly(ethylene terephthalate) has revealed the most efficacious constitutional isomer class and the optimum properties these catalysts should possess. General guidelines for catalyst design are provided.

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.