Qing-Bao Zhang, Feng Li, Bin Pan, Shanshan Zhang, Xiang-Guo Yue and Qiang Liu
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Visible light-induced strain-release transformations of bicyclo[1.1.0]butanes
Bicyclo[1.1.0]butanes, as structurally unique compounds with high strain energy and diverse chemical properties, are becoming increasingly popular building blocks in organic and pharmaceutical chemistries. Strain-release transformation of bicyclo[1.1.0]butanes has received great attention from chemists as it is atom- and step-economical, and significant achievements have been made in this field. Visible-light photocatalysis, with its green and sustainable properties, enriches the strain-release strategy through an electron transfer or energy transfer pathway under mild conditions. In this review, we highlight the latest advancements in visible-light-induced strain-release reactions of bicyclobutanes, with a particular focus on the reaction mechanism. Organization of the content follows a subdivision based on reaction and product classes. Advances in obtaining unique chemical architectures continue to be breakthroughs in this fascinating field of research.
期刊介绍：
ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels.
The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.
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