Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi and Toshio Fuchigami
{"title":"利用带有钯管阴极的流动池开发高效电催化加氢和脱卤系统","authors":"Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi and Toshio Fuchigami","doi":"10.1039/D4GC04617J","DOIUrl":null,"url":null,"abstract":"<p >In order to improve current efficieny, a novel flow and circulation electrolytic system was developed using a Pd tube cathode coated on the inside with Pd black, and packed with Pd catalyst supported on carbon fiber, which is surrounded by a platinum wire anode. This new electrochemical flow system was shown to be highly effective for the cathodic hydrogenation of unsaturated compounds and the dehalogenation of various aromatic halides, including PCB precursors.</p>","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 22","pages":" 11328-11333"},"PeriodicalIF":9.3000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode\",\"authors\":\"Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi and Toshio Fuchigami\",\"doi\":\"10.1039/D4GC04617J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >In order to improve current efficieny, a novel flow and circulation electrolytic system was developed using a Pd tube cathode coated on the inside with Pd black, and packed with Pd catalyst supported on carbon fiber, which is surrounded by a platinum wire anode. This new electrochemical flow system was shown to be highly effective for the cathodic hydrogenation of unsaturated compounds and the dehalogenation of various aromatic halides, including PCB precursors.</p>\",\"PeriodicalId\":78,\"journal\":{\"name\":\"Green Chemistry\",\"volume\":\" 22\",\"pages\":\" 11328-11333\"},\"PeriodicalIF\":9.3000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/gc/d4gc04617j\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/gc/d4gc04617j","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode
In order to improve current efficieny, a novel flow and circulation electrolytic system was developed using a Pd tube cathode coated on the inside with Pd black, and packed with Pd catalyst supported on carbon fiber, which is surrounded by a platinum wire anode. This new electrochemical flow system was shown to be highly effective for the cathodic hydrogenation of unsaturated compounds and the dehalogenation of various aromatic halides, including PCB precursors.
期刊介绍:
Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.