在固相催化剂上气相羰基化甲醇并获得乙酰基：综述

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2024-10-31 DOI:10.1007/s11237-024-09811-x

A. Y. Kapran, Y. I. Pyatnitsky, V. I. Chedryk, S. M. Orlyk

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引用次数: 0

摘要

研究考虑了甲醇气相羰基化的热力学和动力学方面的问题，特别是温度对产物平衡产率的影响和乙酰生产的可能途径。分析了催化剂成分对目标过程的影响、氢气作为气体促进剂对乙酰选择性/产量的影响、串联过程（甲醇分解和羰基化耦合）的特殊性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Vapor-Phase Carbonylation of Methanol with the Obtaining of Acetyls on Solid-Phase Catalysts: A Review

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Vapor-Phase Carbonylation of Methanol with the Obtaining of Acetyls on Solid-Phase Catalysts: A Review

The thermodynamic and kinetic aspects of vapor-phase carbonylation of methanol are considered, in particular the effect of temperature on the equilibrium yield of products and probable routes of acetyls production. The influence of the catalyst composition on the course of the target process, the influence of hydrogen as a gas promoter on the selectivity/yield of acetyls, the peculiarities of the course of the tandem process (coupling of decomposition and carbonylation of methanol) are analyzed.

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来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.