氧化酶和无辅因子氧化酶活化分子氧过程中的自旋轨道相互作用：综述

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2024-10-31 DOI:10.1007/s11237-024-09812-w

B. P. Minaev, T. V. Sakhno, O. O. Panchenko, Y. E. Sakhno

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引用次数: 0

摘要

本文探讨了氧活化过程中无辅因子氧化酶和二氧酶中自旋轨道相互作用的研究现状。通过与含黄素酶以及重要的不依赖于辅助因子的二氧化酶的反应进行比较，分析了燃烧和呼吸过程中三重氧的自旋活化。研究还考虑了葡萄糖氧化酶和一些二氧化酶中的三重小氧转变机制，包括 RuBisCo 氧化酶途径和手性诱导的自旋选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Spin-Orbit Interaction During the Activation of Molecular Oxygen by Oxidases and Cofactor-Free Oxygenases: A Review

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Spin-Orbit Interaction During the Activation of Molecular Oxygen by Oxidases and Cofactor-Free Oxygenases: A Review

The current state of research on spin-orbit interaction in cofactor-free oxidases and dioxygenases during oxygen activation is considered. The spin activation of triplet oxygen during combustion and respiration is analyzed in comparison with the reactions of flavin-containing enzymes, as well as important cofactor-independent dioxygenases. The mechanism of the triplet-singlet transition in glucose oxidase and a number of dioxygenases, including the RuBisCo oxygenase pathway and chirality-induced spin selectivity, is considered.

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来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.