八核 3-苯基-5-(2-吡啶基)吡唑醇/苯基硅倍半氧杂环：合成、独特结构和催化活性

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-11-06 DOI:10.1039/D4DT02690J

Alexey N. Bilyachenko, Victor N. Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel V. Dorovatovskii, Elena S. Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim Ragimov and Di Sun

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引用次数: 0

摘要

第一个含有吡唑吡啶配体的金属硅倍半氧烷，即基于 Cu8 的配合物 1，采用笼状结构，两个环状 Si5 硅倍半氧烷配体夹着两个人字形铜四元分子。1 中的四个 3-苯基-5-（2-吡啶基）吡唑配体具有双重（螯合和桥接）连接原理。化合物 1 在氧化烷烃和醇类时非常活跃。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity†

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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity†

The first metallasilsesquioxane bearing pyrazolylpyridine ligands, the Cu₈-based complex 1, adopts a cage-like structure with two zigzag-type copper tetramers sandwiched by two cyclic Si₅ silsesquioxane ligands. The four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual (chelating and bridging) modes of ligation. Compound 1 is very active in the oxidation of alkanes and alcohols.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.