Xingwu Jiang, Xiang Wang, Peifeng Liu and Jinzheng Huang
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引用次数: 0
摘要
聚酰亚胺(PI)是一种聚合物,具有优异的耐热性、加工性、机械和电气绝缘性能,是先进电介质储能材料的主要候选材料。然而,聚酰亚胺的介电常数较低,阻碍了其更广泛的发展,需要对其进行介电改性。为了提高 PI 的介电常数,研究人员合成并表征了具有极性反式环己烷结构的 PI,然后用纳米 C@BT 纤维对其进行增强,制备出一种新型纳米纤维增强 PI 薄膜。实验结果表明,极性反式环己烷能使纯 PI 薄膜在 100 Hz 频率下的介电常数达到 8.89。同时,C@BT 纤维/改性 PI 复合薄膜的介电常数在 100 Hz 时确实提高到了 39.48,而且 C@BT 纤维的添加量仅为 1.0 wt%,能量存储密度就增加到了 1.028 J/cm3,比纯 PI(0.473 J/cm3)提高了 117.3%。
Novel nano-C@BaTiO3 fibers/polar trans-cyclohexane modified polyimide composite films with enhanced dielectric properties and energy storage density†
Polyimide (PI), a kind of polymer with excellent heat resistance, processing, mechanical and electrical insulation performance, stands out as a prime candidate for advanced dielectric energy storage materials. However, the low dielectric constant of PI has hindered its broader development, requiring dielectric modification. In order to increase the dielectric constant of PI, PI with a polar trans-cyclohexane structure was synthesized and characterized and then reinforced with nano-C@BT-fibers to produce a novel nanofiber reinforced PI film. Experimental results demonstrate that polar trans-cyclohexane enables pure PI films to achieve a dielectric constant of 8.89 at 100 Hz. Meanwhile, the dielectric constant of C@BT-fibers/modified PI composite films was indeed increased up to 39.48 at 100 Hz and the energy storage density increases to 1.028 J cm−3 with only 1.0 wt% addition content of C@BT-fibers, increased by 117.3% compared with that of pure PI (0.473 J cm−3).
期刊介绍:
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.