Namrata Priyadarshini Hota and Sathiyanarayanan Kulathu Iyer
{"title":"用于选择性检测 OCl 离子和生物成像的 N 掺杂碳量子点,以及用于合成取代咪唑† 的 Fe3O4 纳米粒子的生产方法","authors":"Namrata Priyadarshini Hota and Sathiyanarayanan Kulathu Iyer","doi":"10.1039/D4RA06474G","DOIUrl":null,"url":null,"abstract":"<p >Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using <em>o</em>-phenylenediamine and <small>L</small>-tartaric acid. The resultant NCQD produced a high quantum yield (40.3%) and a vivid green fluorescence. They were about 6 nm in size. The NCQD is useful in HeLa cell bioimaging investigations and is used for the fluorescence detection of OCl<small><sup>−</sup></small> ions. The quantum dots' Limit of Detection (LoD) was discovered to be 40 nM. Additionally, cytotoxicity testing was conducted, and we found out that HeLa cells safely endured up to 6.5 mg ml<small><sup>−1</sup></small> of NCQD. Furthermore, NCQDs were employed to synthesize Fe<small><sub>3</sub></small>O<small><sub>4</sub></small> nanoparticles, with the quantum dots acting as a reducing and stabilizing agent. The nanoparticles exhibited remarkable catalytic activity towards organic processes due to their size of 11 nm and surface area of 67.360 m<small><sup>2</sup></small> g<small><sup>−1</sup></small>. Excellent yields of tri-substituted imidazole derivatives were produced using Fe<small><sub>3</sub></small>O<small><sub>4</sub></small> nanoparticles as nanocatalysts in a solvent-free method.</p>","PeriodicalId":102,"journal":{"name":"RSC Advances","volume":" 48","pages":" 35448-35459"},"PeriodicalIF":4.6000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ra/d4ra06474g?page=search","citationCount":"0","resultStr":"{\"title\":\"N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole†\",\"authors\":\"Namrata Priyadarshini Hota and Sathiyanarayanan Kulathu Iyer\",\"doi\":\"10.1039/D4RA06474G\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using <em>o</em>-phenylenediamine and <small>L</small>-tartaric acid. The resultant NCQD produced a high quantum yield (40.3%) and a vivid green fluorescence. They were about 6 nm in size. The NCQD is useful in HeLa cell bioimaging investigations and is used for the fluorescence detection of OCl<small><sup>−</sup></small> ions. The quantum dots' Limit of Detection (LoD) was discovered to be 40 nM. Additionally, cytotoxicity testing was conducted, and we found out that HeLa cells safely endured up to 6.5 mg ml<small><sup>−1</sup></small> of NCQD. Furthermore, NCQDs were employed to synthesize Fe<small><sub>3</sub></small>O<small><sub>4</sub></small> nanoparticles, with the quantum dots acting as a reducing and stabilizing agent. The nanoparticles exhibited remarkable catalytic activity towards organic processes due to their size of 11 nm and surface area of 67.360 m<small><sup>2</sup></small> g<small><sup>−1</sup></small>. Excellent yields of tri-substituted imidazole derivatives were produced using Fe<small><sub>3</sub></small>O<small><sub>4</sub></small> nanoparticles as nanocatalysts in a solvent-free method.</p>\",\"PeriodicalId\":102,\"journal\":{\"name\":\"RSC Advances\",\"volume\":\" 48\",\"pages\":\" 35448-35459\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/ra/d4ra06474g?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"RSC Advances\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra06474g\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC Advances","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra06474g","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole†
Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using o-phenylenediamine and L-tartaric acid. The resultant NCQD produced a high quantum yield (40.3%) and a vivid green fluorescence. They were about 6 nm in size. The NCQD is useful in HeLa cell bioimaging investigations and is used for the fluorescence detection of OCl− ions. The quantum dots' Limit of Detection (LoD) was discovered to be 40 nM. Additionally, cytotoxicity testing was conducted, and we found out that HeLa cells safely endured up to 6.5 mg ml−1 of NCQD. Furthermore, NCQDs were employed to synthesize Fe3O4 nanoparticles, with the quantum dots acting as a reducing and stabilizing agent. The nanoparticles exhibited remarkable catalytic activity towards organic processes due to their size of 11 nm and surface area of 67.360 m2 g−1. Excellent yields of tri-substituted imidazole derivatives were produced using Fe3O4 nanoparticles as nanocatalysts in a solvent-free method.
期刊介绍:
An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.