{"title":"缺陷和分层孔 Zr 金属有机框架材料的微流控合成及二氧化碳吸附性能研究","authors":"Xuehui Ge, Zihan Liu, Nanjie Wei, Xiaocheng Lin* and Cejun Hu*, ","doi":"10.1021/acs.cgd.4c0110610.1021/acs.cgd.4c01106","DOIUrl":null,"url":null,"abstract":"<p >Microfluidic synthesis has emerged as a promising method for synthesizing metal–organic frameworks (MOFs). It overcomes the limitations of the traditional solvothermal method to regulate the structure and function of the MOFs. This study synthesized various MOFs with different structures and functions by controlling the reaction time and the ratio of metal ions to organic ligands through microfluidics and investigated their CO<sub>2</sub> adsorption properties. The results showed that the microfluidic synthesized defective and hierarchical pore MOF-808 improved the adsorption performance of CO<sub>2</sub> by nearly 110% and 30%, respectively, compared with solvothermal synthesized MOF-808.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microfluidic Synthesis of Defective and Hierarchical Pore Zr Metal–Organic Framework Materials and CO2 Adsorption Performance Study\",\"authors\":\"Xuehui Ge, Zihan Liu, Nanjie Wei, Xiaocheng Lin* and Cejun Hu*, \",\"doi\":\"10.1021/acs.cgd.4c0110610.1021/acs.cgd.4c01106\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Microfluidic synthesis has emerged as a promising method for synthesizing metal–organic frameworks (MOFs). It overcomes the limitations of the traditional solvothermal method to regulate the structure and function of the MOFs. This study synthesized various MOFs with different structures and functions by controlling the reaction time and the ratio of metal ions to organic ligands through microfluidics and investigated their CO<sub>2</sub> adsorption properties. The results showed that the microfluidic synthesized defective and hierarchical pore MOF-808 improved the adsorption performance of CO<sub>2</sub> by nearly 110% and 30%, respectively, compared with solvothermal synthesized MOF-808.</p>\",\"PeriodicalId\":3,\"journal\":{\"name\":\"ACS Applied Electronic Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Electronic Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01106\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01106","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Microfluidic Synthesis of Defective and Hierarchical Pore Zr Metal–Organic Framework Materials and CO2 Adsorption Performance Study
Microfluidic synthesis has emerged as a promising method for synthesizing metal–organic frameworks (MOFs). It overcomes the limitations of the traditional solvothermal method to regulate the structure and function of the MOFs. This study synthesized various MOFs with different structures and functions by controlling the reaction time and the ratio of metal ions to organic ligands through microfluidics and investigated their CO2 adsorption properties. The results showed that the microfluidic synthesized defective and hierarchical pore MOF-808 improved the adsorption performance of CO2 by nearly 110% and 30%, respectively, compared with solvothermal synthesized MOF-808.
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