{"title":"氧化石墨烯、淀粉和牛皮纸木质素生物纳米复合控释磷肥:对磷肥管理和玉米生长的影响","authors":"Badr-Eddine Channab , Fatima Tayi , Meryem Aqlil , Adil Akil , Younes Essamlali , Achraf Chakir , Mohamed Zahouily","doi":"10.1016/j.ijbiomac.2024.137190","DOIUrl":null,"url":null,"abstract":"<div><div>This study focuses on the synthesis and practical application of bio-nanocomposite films made from a mixture of starch (ST) and Kraft lignin (KL) with graphene oxide (GO) nanoparticles. FTIR, XRD, Raman, SEM, and TEM analysis confirmed the synthesis's success of GO. The bio-nanocomposites were used as advanced coatings for triple superphosphate (TSP) fertilizers, and their implications for maize (<em>Zea mays</em> L.) plant growth were examined. Incorporating GO into the composite matrix is a significant accomplishment of this study, as demonstrated by the noticeable changes observed in the FTIR spectra, indicating consequent structural changes. Morphological analyses conducted by SEM reveal changes in the surface characteristics of the ST/KL films, providing essential information about the structural details of the bio-nanocomposite. The utilization of precision-coated TSP fertilizers leads to a significant enhancement in mechanical strength, as demonstrated by the improved crush resistance. Furthermore, these formulations guarantee a gradual release of phosphorus, showcasing their potential for efficient nutrient management in agricultural settings. The study examines the practical application of coated TSP fertilizers in agriculture and their positive effects on various growth parameters of Maize (<em>Zea mays</em> L.) plants. Using these fertilizers promotes sustainable and efficient agricultural practices, contributing to developing innovative agrochemical solutions.</div></div>","PeriodicalId":333,"journal":{"name":"International Journal of Biological Macromolecules","volume":"282 ","pages":"Article 137190"},"PeriodicalIF":7.7000,"publicationDate":"2024-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Graphene oxide, starch, and kraft lignin bio-nanocomposite controlled-release phosphorus fertilizer: Effect on P management and maize growth\",\"authors\":\"Badr-Eddine Channab , Fatima Tayi , Meryem Aqlil , Adil Akil , Younes Essamlali , Achraf Chakir , Mohamed Zahouily\",\"doi\":\"10.1016/j.ijbiomac.2024.137190\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study focuses on the synthesis and practical application of bio-nanocomposite films made from a mixture of starch (ST) and Kraft lignin (KL) with graphene oxide (GO) nanoparticles. FTIR, XRD, Raman, SEM, and TEM analysis confirmed the synthesis's success of GO. The bio-nanocomposites were used as advanced coatings for triple superphosphate (TSP) fertilizers, and their implications for maize (<em>Zea mays</em> L.) plant growth were examined. Incorporating GO into the composite matrix is a significant accomplishment of this study, as demonstrated by the noticeable changes observed in the FTIR spectra, indicating consequent structural changes. Morphological analyses conducted by SEM reveal changes in the surface characteristics of the ST/KL films, providing essential information about the structural details of the bio-nanocomposite. The utilization of precision-coated TSP fertilizers leads to a significant enhancement in mechanical strength, as demonstrated by the improved crush resistance. Furthermore, these formulations guarantee a gradual release of phosphorus, showcasing their potential for efficient nutrient management in agricultural settings. The study examines the practical application of coated TSP fertilizers in agriculture and their positive effects on various growth parameters of Maize (<em>Zea mays</em> L.) plants. Using these fertilizers promotes sustainable and efficient agricultural practices, contributing to developing innovative agrochemical solutions.</div></div>\",\"PeriodicalId\":333,\"journal\":{\"name\":\"International Journal of Biological Macromolecules\",\"volume\":\"282 \",\"pages\":\"Article 137190\"},\"PeriodicalIF\":7.7000,\"publicationDate\":\"2024-11-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Biological Macromolecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0141813024079996\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Biological Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0141813024079996","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
引用次数: 0
摘要
本研究的重点是淀粉(ST)和牛皮纸木质素(KL)与氧化石墨烯(GO)纳米粒子混合物制成的生物纳米复合薄膜的合成和实际应用。傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)、拉曼光谱(Raman)、扫描电镜(SEM)和电子显微镜(TEM)分析证实了 GO 的成功合成。生物纳米复合材料被用作三过磷酸钙(TSP)肥料的高级涂层,并研究了其对玉米(Zea mays L.)植物生长的影响。傅立叶变换红外光谱中观察到的明显变化表明,将 GO 加入到复合基质中是本研究的一项重要成果,这也表明了随之而来的结构变化。通过扫描电镜进行的形态分析表明,ST/KL 薄膜的表面特征发生了变化,提供了有关生物纳米复合材料结构细节的重要信息。使用精密涂层的 TSP 肥料可显著提高机械强度,抗压性能的改善就证明了这一点。此外,这些配方还能保证磷的逐步释放,展示了其在农业环境中进行高效养分管理的潜力。本研究探讨了包衣 TSP 肥料在农业中的实际应用及其对玉米(Zea mays L.)植物各种生长参数的积极影响。使用这些肥料可促进可持续和高效的农业实践,有助于开发创新的农用化学品解决方案。
Graphene oxide, starch, and kraft lignin bio-nanocomposite controlled-release phosphorus fertilizer: Effect on P management and maize growth
This study focuses on the synthesis and practical application of bio-nanocomposite films made from a mixture of starch (ST) and Kraft lignin (KL) with graphene oxide (GO) nanoparticles. FTIR, XRD, Raman, SEM, and TEM analysis confirmed the synthesis's success of GO. The bio-nanocomposites were used as advanced coatings for triple superphosphate (TSP) fertilizers, and their implications for maize (Zea mays L.) plant growth were examined. Incorporating GO into the composite matrix is a significant accomplishment of this study, as demonstrated by the noticeable changes observed in the FTIR spectra, indicating consequent structural changes. Morphological analyses conducted by SEM reveal changes in the surface characteristics of the ST/KL films, providing essential information about the structural details of the bio-nanocomposite. The utilization of precision-coated TSP fertilizers leads to a significant enhancement in mechanical strength, as demonstrated by the improved crush resistance. Furthermore, these formulations guarantee a gradual release of phosphorus, showcasing their potential for efficient nutrient management in agricultural settings. The study examines the practical application of coated TSP fertilizers in agriculture and their positive effects on various growth parameters of Maize (Zea mays L.) plants. Using these fertilizers promotes sustainable and efficient agricultural practices, contributing to developing innovative agrochemical solutions.
期刊介绍:
The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.