通过低温打浆和部分溶解玉米秸秆制备出具有高效甲醛吸附功能的全纤维素空气过滤器。

IF 7.7 1区 化学 Q1 BIOCHEMISTRY & MOLECULAR BIOLOGY
Xingyu Wang, Qiuyue Hu, Xueping Wang, Xiaoran Zhang, Tian Si, Xin Gao, Lincai Peng, Keli Chen, Heng Zhang
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引用次数: 0

摘要

工业和农业焚烧产生的颗粒物(PM)排放已成为一个重大的公共健康问题。此外,每年生产的大量秸秆仍未得到充分利用,尤其是在中国。在这项研究中,我们提出了一种利用玉米秸秆通过低温蒽醌制浆、部分溶解和高速剪切诱导再生生产全纤维素空气过滤器的新方法。全纤维素保留了玉米秸秆中约 61.40%-78.23% 的半纤维素,而且在空气过滤器低温(2.5 渗透率(0.12%)和压降(14.3 Pa)条件下,脱木素率高达 81.63%-92.51%,同时表现出 54.5 mg/g 的显著甲醛吸附能力。此外,还获得了再生纤维素的高结晶度指数和坚固的微/纳米结构。这项研究为气态甲醛吸附引入了一种创新而简便的策略,并为农业废弃物的利用提供了新的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A holocellulose air filter with highly efficient formaldehyde adsorption prepared via low temperature pulping and partial dissolving from corn stalks.

Emissions of particulate matter (PM) originating from industrial and agricultural incineration had emerged as a significant public health concern. Furthermore, the considerable annual production of straw remains underutilized, particularly in China. In this study, we proposed a novel approach for holocellulose air filter production from corn stalks via low-temperature anthraquinone pulping, partial dissolving, and high-speed shear-induced regeneration. About 61.40-78.23 % of hemicellulose in corn stalks was retained in holocellulose, furthermore, the delignification rate was up to 81.63-92.51 % after low temperature (<100 °C) alkaline exactment. Subsequently, holocellulose air filters (RHF) was prepared through regeneration with high-speed shear induced (25,000 rpm) and freeze-drying. The final air filters contained approximately 8.56-12.4 % hemicellulose, exhibiting a substantial adsorption capacity for low molecules such as formaldehyde. The results revealed remarkably low PM2.5 penetration ratio (0.12 %) and pressure drop (14.3 Pa) of the air filter, while exhibiting a remarkable formaldehyde adsorption capacity of 54.5 mg/g. Moreover, the characters of high crystallinity index and robust micro/nano-structure of regenerated cellulose were obtained. This study introduced an innovative and facile strategy for gaseous formaldehyde adsorption and introduced novel solutions for agricultural waste utilization.

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来源期刊
International Journal of Biological Macromolecules
International Journal of Biological Macromolecules 生物-生化与分子生物学
CiteScore
13.70
自引率
9.80%
发文量
2728
审稿时长
64 days
期刊介绍: The International Journal of Biological Macromolecules is a well-established international journal dedicated to research on the chemical and biological aspects of natural macromolecules. Focusing on proteins, macromolecular carbohydrates, glycoproteins, proteoglycans, lignins, biological poly-acids, and nucleic acids, the journal presents the latest findings in molecular structure, properties, biological activities, interactions, modifications, and functional properties. Papers must offer new and novel insights, encompassing related model systems, structural conformational studies, theoretical developments, and analytical techniques. Each paper is required to primarily focus on at least one named biological macromolecule, reflected in the title, abstract, and text.
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