{"title":"基于纤维素的透明复合膜与功能集成,具有潜在的农业应用价值","authors":"Tao Zhang, Jiali Ran, Yu Chen, Xiao Zhang, Yannan Chen, Fengxian Qiu","doi":"10.1007/s12221-024-00718-x","DOIUrl":null,"url":null,"abstract":"<div><p>Within the realm of sustainable agriculture, there is a growing focus on the development of biodegradable plastic coverings in response to the adverse environmental impact stemming from contamination by fossil-based plastic film. Herein, a function-integrated cellulose-based composite film was innovatively designed for agricultural insulation applications. Lignocellulosic nanofibers (LCNF) and hollow SiO<sub>2</sub> microspheres are blended to construct LCNF/SiO<sub>2</sub> composite films with multistage nanocavity structures. Meanwhile, the hexadecyltrimethoxysilane modification further promotes the integration of hydrophobic function and the encapsulated function of hollow SiO<sub>2</sub> microspheres in the composite film to form the hydrophobic LCNF/SiO<sub>2</sub> (H-LCNF/SiO<sub>2</sub>) composite film. Owing to the small size effect of SiO<sub>2</sub> microspheres and the nanocavity structure, the resulting film exhibits a low thermal conductivity (0.07 ± 0.002 W/(m·K)) and excellent optical properties of the UV–Vis transmission with transparency of over 77% (above 600 nm). Furthermore, H-LCNF/SiO<sub>2</sub> composite film displays acceptable mechanical properties with tensile strength of 56.03 MPa and elongation at a break of 6.10%, respectively. Notably, the composite film acquires excellent flexibility, water-proofing, water vapor permeability, and biodegradable performances, improving agricultural applications. Therefore, this work provides a lignocellulose-based film with functional integration that differs from traditional agricultural films by constructing a hollow structure to achieve thermal protection, with the advantage of being more energy efficient and environmentally friendly, promising potential applications in agriculture.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4137 - 4147"},"PeriodicalIF":2.2000,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Transparent Cellulose-Based Composite Film with Functional Integration for Potential Agriculture Application\",\"authors\":\"Tao Zhang, Jiali Ran, Yu Chen, Xiao Zhang, Yannan Chen, Fengxian Qiu\",\"doi\":\"10.1007/s12221-024-00718-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Within the realm of sustainable agriculture, there is a growing focus on the development of biodegradable plastic coverings in response to the adverse environmental impact stemming from contamination by fossil-based plastic film. Herein, a function-integrated cellulose-based composite film was innovatively designed for agricultural insulation applications. Lignocellulosic nanofibers (LCNF) and hollow SiO<sub>2</sub> microspheres are blended to construct LCNF/SiO<sub>2</sub> composite films with multistage nanocavity structures. Meanwhile, the hexadecyltrimethoxysilane modification further promotes the integration of hydrophobic function and the encapsulated function of hollow SiO<sub>2</sub> microspheres in the composite film to form the hydrophobic LCNF/SiO<sub>2</sub> (H-LCNF/SiO<sub>2</sub>) composite film. Owing to the small size effect of SiO<sub>2</sub> microspheres and the nanocavity structure, the resulting film exhibits a low thermal conductivity (0.07 ± 0.002 W/(m·K)) and excellent optical properties of the UV–Vis transmission with transparency of over 77% (above 600 nm). Furthermore, H-LCNF/SiO<sub>2</sub> composite film displays acceptable mechanical properties with tensile strength of 56.03 MPa and elongation at a break of 6.10%, respectively. Notably, the composite film acquires excellent flexibility, water-proofing, water vapor permeability, and biodegradable performances, improving agricultural applications. Therefore, this work provides a lignocellulose-based film with functional integration that differs from traditional agricultural films by constructing a hollow structure to achieve thermal protection, with the advantage of being more energy efficient and environmentally friendly, promising potential applications in agriculture.</p></div>\",\"PeriodicalId\":557,\"journal\":{\"name\":\"Fibers and Polymers\",\"volume\":\"25 11\",\"pages\":\"4137 - 4147\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-09-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fibers and Polymers\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12221-024-00718-x\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, TEXTILES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fibers and Polymers","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12221-024-00718-x","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, TEXTILES","Score":null,"Total":0}
Transparent Cellulose-Based Composite Film with Functional Integration for Potential Agriculture Application
Within the realm of sustainable agriculture, there is a growing focus on the development of biodegradable plastic coverings in response to the adverse environmental impact stemming from contamination by fossil-based plastic film. Herein, a function-integrated cellulose-based composite film was innovatively designed for agricultural insulation applications. Lignocellulosic nanofibers (LCNF) and hollow SiO2 microspheres are blended to construct LCNF/SiO2 composite films with multistage nanocavity structures. Meanwhile, the hexadecyltrimethoxysilane modification further promotes the integration of hydrophobic function and the encapsulated function of hollow SiO2 microspheres in the composite film to form the hydrophobic LCNF/SiO2 (H-LCNF/SiO2) composite film. Owing to the small size effect of SiO2 microspheres and the nanocavity structure, the resulting film exhibits a low thermal conductivity (0.07 ± 0.002 W/(m·K)) and excellent optical properties of the UV–Vis transmission with transparency of over 77% (above 600 nm). Furthermore, H-LCNF/SiO2 composite film displays acceptable mechanical properties with tensile strength of 56.03 MPa and elongation at a break of 6.10%, respectively. Notably, the composite film acquires excellent flexibility, water-proofing, water vapor permeability, and biodegradable performances, improving agricultural applications. Therefore, this work provides a lignocellulose-based film with functional integration that differs from traditional agricultural films by constructing a hollow structure to achieve thermal protection, with the advantage of being more energy efficient and environmentally friendly, promising potential applications in agriculture.
期刊介绍:
-Chemistry of Fiber Materials, Polymer Reactions and Synthesis-
Physical Properties of Fibers, Polymer Blends and Composites-
Fiber Spinning and Textile Processing, Polymer Physics, Morphology-
Colorants and Dyeing, Polymer Analysis and Characterization-
Chemical Aftertreatment of Textiles, Polymer Processing and Rheology-
Textile and Apparel Science, Functional Polymers