热处理木材表面 Ce/TiO2/BTA-HALS 涂层的制备和人工风化特性

IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING
Dong Xing , Boshuai Fan
{"title":"热处理木材表面 Ce/TiO2/BTA-HALS 涂层的制备和人工风化特性","authors":"Dong Xing ,&nbsp;Boshuai Fan","doi":"10.1016/j.indcrop.2024.119936","DOIUrl":null,"url":null,"abstract":"<div><div>Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO<sub>2</sub>) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (<em>ΔE</em>) of Ce/TiO<sub>2</sub>/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":"222 ","pages":"Article 119936"},"PeriodicalIF":5.6000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and artificial weathering properties of Ce/TiO2/BTA-HALS coating on heat-treated wood surface\",\"authors\":\"Dong Xing ,&nbsp;Boshuai Fan\",\"doi\":\"10.1016/j.indcrop.2024.119936\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO<sub>2</sub>) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (<em>ΔE</em>) of Ce/TiO<sub>2</sub>/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.</div></div>\",\"PeriodicalId\":13581,\"journal\":{\"name\":\"Industrial Crops and Products\",\"volume\":\"222 \",\"pages\":\"Article 119936\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial Crops and Products\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0926669024019137\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial Crops and Products","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926669024019137","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
引用次数: 0

摘要

经过热处理的木材只有短期的耐候性,而在长期的户外环境中会出现木材开裂、褪色等问题。因此,有必要提高热处理木材的抗风化性能。本研究采用简单的物理混合方法,将有机紫外线吸收剂、光稳定剂和无机二氧化铈/二氧化钛(Ce/TiO2)紫外线屏蔽剂复配,并通过刷涂方法将改性剂涂覆在热处理木材表面。紫外可见光谱显示,复合涂层具有很高的透明度和紫外线屏蔽性能。人工风化后,Ce/TiO2/BTA-HALS 涂层样品的色差(ΔE)仅为 1.64 和 2.68,明显低于热处理样品的 2.3 和 6.1。表面粗糙度、扫描电子显微镜和 X 射线能谱也表明,涂层的稳定性明显提高,无机颗粒的损失减少。傅立叶变换红外光谱和电子顺磁共振证明改性剂成功接枝到了热处理木材的表面。该复合涂层对提高热处理木材的耐候性有一定的协同作用,改善了改性剂的成膜性和涂层在风化过程中的稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and artificial weathering properties of Ce/TiO2/BTA-HALS coating on heat-treated wood surface
Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO2) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (ΔE) of Ce/TiO2/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Industrial Crops and Products
Industrial Crops and Products 农林科学-农业工程
CiteScore
9.50
自引率
8.50%
发文量
1518
审稿时长
43 days
期刊介绍: Industrial Crops and Products is an International Journal publishing academic and industrial research on industrial (defined as non-food/non-feed) crops and products. Papers concern both crop-oriented and bio-based materials from crops-oriented research, and should be of interest to an international audience, hypothesis driven, and where comparisons are made statistics performed.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信