二硫化钨(WS2)与铁钴碲锆(FeCoTeZr)的协同界面工程,用于超级电池设备

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
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引用次数: 0

摘要

人们对可再生能源的依赖程度越来越高,这加剧了对先进储能技术的需求。混合储能装置(HESD)是一种很有前景的方法,它兼具功率密度和能量密度。在这项研究中,通过引入铁钴碲锆(FeCoTeZr)合金作为界面层,提高了二硫化钨(WS2)的储能性能。该层采用无粘结剂磁控溅射方法沉积,解决了泡沫镍(NF)基底和 WS2 之间的导电率不匹配问题,显著提高了器件性能。研究人员获得了制备样品的结构特征(SEM、XRD、拉曼和 EDX)和电化学活性(CV、GCD 和 EIS)。随后,在实际装置中将这些电极用作法拉第电极,并与活性炭一起用作电化学双层电容器(EDLC)电极。高效 WS₂/FeCoTeZr 器件的能量密度达到 55 Wh/kg,功率密度达到 4250 W/kg,同时在 3000 次 GCD 循环后仍能保持 97.9% 的容量。此外,还利用两种建模技术分析了该器件的电容和扩散行为。这种新颖的策略强调了界面层增强型 HESD 作为未来储能系统尖端解决方案的巨大潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synergistic interface engineering of tungsten disulfide (WS2) with iron-cobalt-tellurium-zirconium (FeCoTeZr) for supercapattery devices
The increasing reliance on renewable energy sources has intensified the need for advanced energy storage technologies. Hybrid energy storage devices (HESDs) present a promising approach, combining both power and energy density. In this study, the energy storage performance of tungsten disulfide (WS2) is enhanced by introducing an iron-cobalt-tellurium-zirconium (FeCoTeZr) alloy as an interfacial layer. This layer, deposited using a binder-free magnetron sputtering method, resolves the conductivity mismatch between the nickel foam (NF) substrate and WS2, significantly improving device performance. The structural characteristics (SEM, XRD, Raman, and EDX) and electrochemical activities (CV, GCD, and EIS) of the prepared samples were acquired. The electrodes were subsequently used as a faradaic-dominated electrode in conjunction with activated carbon as electrochemical double-layer capacitor (EDLC) electrode in a real device. The high-efficiency WS₂/FeCoTeZr device achieved an energy density of 55 Wh/kg and a power density of 4250 W/kg, while retaining 97.9 % of its capacity after 3000 GCD cycles. Additionally, the device's capacitive and diffusive behaviors were analyzed using two modeling techniques. This novel strategy emphasizes the significant potential of interfacial-layer-enhanced HESDs as a cutting-edge solution for future energy storage systems.
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来源期刊
Journal of Physics and Chemistry of Solids
Journal of Physics and Chemistry of Solids 工程技术-化学综合
CiteScore
7.80
自引率
2.50%
发文量
605
审稿时长
40 days
期刊介绍: The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems. Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal: Low-dimensional systems Exotic states of quantum electron matter including topological phases Energy conversion and storage Interfaces, nanoparticles and catalysts.
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